Product

2-Amino-6-bromobenzothiazole

CAS No.：15864-32-1

Other grades of this product :

2-Amino-6-bromobenzothiazole Basic information

Product Name:	2-Amino-6-bromobenzothiazole
Synonyms:	6-Bromobenzothiazole-2-ylamine;2-BenzothiazolaMine, 6-broMo-;6-BroMo-2-AMino Benzo Thiazole;6-BroMobenzo thiazole-2-aMine;2-Amino-6-bromobenzothiazole,98%;2-Amino-6-bromobenzothiazole 97%;Benzothiazole, 2-amino-6-bromo-;6-bromo-2-benzothiazolamin
CAS:	15864-32-1
MF:	C7H5BrN2S
MW:	229.1
EINECS:
Product Categories:	Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;Thiazoles;ThiazolesHeterocyclic Building Blocks
Mol File:	15864-32-1.mol

2-Amino-6-bromobenzothiazole Chemical Properties

Melting point	213-217 °C (lit.)
Boiling point	366.8±34.0 °C(Predicted)
density	1.836±0.06 g/cm3(Predicted)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	soluble in Methanol
pka	3.30±0.10(Predicted)
form	Powder
color	White
CAS DataBase Reference	15864-32-1(CAS DataBase Reference)
NIST Chemistry Reference	2-Amino-6-bromobenzothiazole(15864-32-1)
EPA Substance Registry System	2-Benzothiazolamine, 6-bromo- (15864-32-1)

Safety Information

Hazard Codes	Xn,Xi
Risk Statements	22-36-43
Safety Statements	26-36/37
WGK Germany	3
TSCA	Yes
HazardClass	IRRITANT
HS Code	29342000

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

2-Amino-6-bromobenzothiazole Usage And Synthesis

Chemical Properties	white to light yellow crystal powde
Uses	2-Amino-6-bromobenzothiazole may be used in the synthesis of the following 2-amino-6-arylbenzothiazole compounds: 6-p-tolylbenzo[d]thiazole-2-amine 6-(4chlorophenyl)benzo[d]thiazole-2-amine 6-(4-methoxyphenyl)benzo[d]thiazole-2-amine 6-(3,5-bis(triflouromethyl)phenyl)benzo[d]thiazole-2-amine 6-phenylbenzo[d]thiazole-2-amine It may be employed as a ligand (L) in the synthesis of organometallic derivatives of Rh(I) [Rh(CO)₂(L)(Cl)].
General Description	Reaction of 4-bromoaniline with acetic acid and potassium thiocynate in solution of bromine in acetic acid yields 2-amino-6-bromobenzothiazole. 2-Amino-6-bromobenzothiazole can also be synthesized from 2-aminobenzothiazole via monobromination with silica-supported quinolinium tribromide.

2-Amino-6-bromobenzothiazole Preparation Products And Raw materials

Raw materials	Sodium hydroxide-->Acetic acid-->Government regulation-->Sodium thiocyanate-->4-Bromoaniline-->2-Amino-7-bromobenzothiazole-->1-(3-BROMOPHENYL)-2-THIOUREA
Preparation Products	6-BROMO-2-METHYL-1,3-BENZOTHIAZOLE

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