| 4-Nitrodiphenylamine Basic information |
| Product Name: | 4-Nitrodiphenylamine |
| Synonyms: | 4-nitro-n-phenylbenzenamine;4-nitro-N-phenyl-benzenamine;Benzenamine, 4-nitro-N-phenyl-;diphenyl,4-nitro-amin;Diphenylamine, 4-nitro-;N-(4-Nitrophenyl)-N-phenylamine;p-Nitrophenylphenylamine;(4-NITROPHENYL)PHENYLAMINE |
| CAS: | 836-30-6 |
| MF: | C12H10N2O2 |
| MW: | 214.22 |
| EINECS: | 212-646-2 |
| Product Categories: | Aromatics Compounds;Aromatics;Intermediates of Dyes and Pigments;Amines;C11 to C38;Nitrogen Compounds |
| Mol File: | 836-30-6.mol |
| 4-Nitrodiphenylamine Chemical Properties |
| Melting point | 132-135 °C (lit.) |
| Boiling point | 211 °C (30 mmHg) |
| density | 1.2042 (rough estimate) |
| refractive index | 1.6660 (estimate) |
| Fp | 190°C |
| storage temp. | Refrigerator |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Solid |
| pka | -2.60±0.20(Predicted) |
| color | Orange to Brown |
| Water Solubility | INSOLUBLE |
| BRN | 2051910 |
| CAS DataBase Reference | 836-30-6(CAS DataBase Reference) |
| NIST Chemistry Reference | N-(4-Nitrophenyl)-N-phenylamine(836-30-6) |
| EPA Substance Registry System | 4-Nitrodiphenylamine (836-30-6) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39-36 |
| RIDADR | 3077 |
| WGK Germany | 3 |
| RTECS | JJ9600000 |
| Hazard Note | Irritant |
| TSCA | Yes |
| HazardClass | 9 |
| PackingGroup | III |
| HS Code | 29214400 |
| Hazardous Substances Data | 836-30-6(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| 4-Nitrodiphenylamine | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 4-Nitrodiphenylamine Usage And Synthesis |
| Chemical Properties | Orange Crystalline Solid |
| Uses | 4-Nitrodiphenylamine was used to study reduction of nitrated diphenylamine derivatives in sediment water batch enrichments and dense cell suspensions of anaerobic, aromatic-compound-mineralizing pure bacterial cultures. |
| Synthesis Reference(s) | The Journal of Organic Chemistry, 42, p. 1786, 1977 DOI: 10.1021/jo00430a025 |
| General Description | 4-Nitrodiphenylamine undergoes heterogeneous catalytic transfer hydrogenation to form p-phenylenediamines. 4-Nitrodiphenylamine is used as stabilizer for propellants and explosives. |
| Purification Methods | Crystallise the amine from EtOH or aqueous EtOH (m 135-136o) and has m 131.5-132o after sublimation in vacuo. [Beilstein 12 H 715, 12 III 1586.] |
| 4-Nitrodiphenylamine Preparation Products And Raw materials |
| Raw materials | 2-Nitrodiphenylamine-->2-(Methylamino)pyridine-->Nitrobenzene |
| Preparation Products | 4-Aminodiphenylamine-->Disperse Orange 97-->Amoscanate-->Disperse Orange 97 |
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