1-Fluoro-3-nitrobenzene

CAS No.：402-67-5

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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1-Fluoro-3-nitrobenzene Basic information

Product Name:	1-Fluoro-3-nitrobenzene
Synonyms:	Benzene,1-fluoro-3-nitro-;1-FLUORO-3-NITROBENZENE;3-FLUORONITROBENZENE;3-FLUORO-1-NITROBENZENE;Inter-Fluoride Nitrobenzene;Fluoronitrobenzene2;1-Fluoro-3-nitrobenzene,98+%;M-NITROFLUOROBENZENE
CAS:	402-67-5
MF:	C6H4FNO2
MW:	141.1
EINECS:	206-953-0
Product Categories:	Nitro Compounds;Nitrogen Compounds;Fluoro-Aromatics;Fluorine Compounds;Nitro Compounds;Organic Building Blocks
Mol File:	402-67-5.mol

1-Fluoro-3-nitrobenzene Chemical Properties

Melting point	1.7 °C (lit.)
Boiling point	205 °C (lit.)
density	1.325 g/mL at 25 °C (lit.)
refractive index	n20/D 1.525(lit.)
RTECS	DA1385000
Fp	170 °F
storage temp.	Inert atmosphere,2-8°C
form	clear liquid
Specific Gravity	1.325
color	green-yellow
Water Solubility	immiscible
BRN	1862210
CAS DataBase Reference	402-67-5(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-3-nitro-(402-67-5)

Safety Information

Hazard Codes	T,Xi,Xn
Risk Statements	23/24/25-33-20/21/22
Safety Statements	36/37-45-36
RIDADR	UN 2810 6.1/PG 2
WGK Germany	3
Hazard Note	Toxic/Irritant
HazardClass	6.1
PackingGroup	III
HS Code	29049085

MSDS Information

Provider	Language
3-Fluoronitrobenzene	English
ACROS	English
SigmaAldrich	English
ALFA	English

1-Fluoro-3-nitrobenzene Usage And Synthesis

Chemical Properties	clear brown liquid
Uses	1-Fluoro-3-nitrobenzene is a di-substitiuted benzene derivative used for the synthesis of fluoroaromatic compounds through fluorodenitration and other pharmaceuticals.
Uses	1-Fluoro-3-nitrobenzene was used as an internal standard in the regiospecific silver-mediated fluorination of aryl silanes.

1-Fluoro-3-nitrobenzene Preparation Products And Raw materials

Raw materials	2,5-Difluoronitrobenzene-->3,4-Difluoronitrobenzene-->Nitrobenzene-->1-Fluoro-2-nitrobenzene-->4-Fluoronitrobenzene-->Benzenediazonium, 3-nitro-, tetrafluoroborate(1-)-->2-Fluoro-4-nitroaniline-->Benzenesulfonyl fluoride, 3-fluoro--->3-Fluorophenylboronic acid-->2,4-Dichloronitrobenzene-->3-Nitrobenzenesulfonyl chloride
Preparation Products	3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER-->3-(4-Morpholinyl)aniline-->1-(3-NITROPHENYL)-PIPERAZINE-->3-PHENOXYANILINE-->1-METHYL-4-(3-NITROPHENYL)PIPERAZINE-->3-(1H-PYRAZOL-1-YL)ANILINE-->3-(4-Methylpiperazin-1-yl)aniline-->1-BROMO-4-FLUORO-2-NITROBENZENE

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