Bis(acetonitrile)dichloropalladium(II)

Bis(acetonitrile)dichloropalladium(II)
  • CAS No.:14592-56-4
Other grades of this product :
Bis(acetonitrile)dichloropalladium(II) Basic information
Reaction
Product Name:Bis(acetonitrile)dichloropalladium(II)
Synonyms:PALLADIUM(II) CHLORIDE-DIACETONITRILE COMPLEX;PALLADIUM-BIS-ACETONITRIL-DICHLORIDE;PALLADIUM DICHLOROBIS(ACETONITRILE);TRANS-DICHLOROBIS(ACETONITRILE)PALLADIUM;TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;Bis(acetonitriL;e)dichL;PALLADIUM(2+) ION BIS(ACETONITRILE) DICHLORIDE
CAS:14592-56-4
MF:C4H6Cl2N2Pd
MW:259.43
EINECS:238-637-3
Product Categories:Pd;organometallic complexes;Metal Compounds;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes
Mol File:14592-56-4.mol
Bis(acetonitrile)dichloropalladium(II) Chemical Properties
Melting point 300 °C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in acetonitrile, acetone, chloroform
form Fine Crystalline Powder
color Orange to rust-brown
Water Solubility insoluble
CAS DataBase Reference14592-56-4(CAS DataBase Reference)
Safety Information
Hazard Codes T,Xn
Risk Statements 23/24/25-36/37/38-20/21/22
Safety Statements 16-27-36/37-45-36-26
RIDADR UN 3077 9/PG 3
WGK Germany 3
TSCA No
HazardClass 6.1
PackingGroup III
HS Code 28439090
MSDS Information
ProviderLanguage
Bis(acetonitrile)dichloropalladium(II) English
SigmaAldrich English
ACROS English
ALFA English
Bis(acetonitrile)dichloropalladium(II) Usage And Synthesis
Reaction
  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
  8. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.
Chemical Propertiesdark yellow powder
Usessuzuki reaction
UsesIt is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.
UsesCatalyst used in an ether-directed aza-Claisen rearrangement.
General DescriptionThis product has been enhanced for catalytic efficiency.
Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials
Raw materialsDichloromethane-->Acetonitrile-->Palladium chloride

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