| Bis-(triphenylphosphino)-cuprous borohydride Basic information |
| Product Name: | Bis-(triphenylphosphino)-cuprous borohydride |
| Synonyms: | Bis(triphenylphosphine)copper Tetrahydroborate, (PPh3)2CuBH4;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYD;Copper,[tetrahydroborato(1-)-kH,kH']bis(triphenylphosphine)-,(T-4)-;BIS(TRIPHENYLPHOSPHINE)COPPER(I) BOROHYDRIDE;BIS(TRIPHENYLPHOSPHINE)COPPER(I) TETRAHYDRIDOBORATE;BIS(TRIPHENYLPHOSPHINE)COPPER TETRAHYDROBORATE;bis-(triphenylphosphino)-cuprous borohydride;Copper bis(trimethylphosphine)(tetrahydroborate) |
| CAS: | 16903-61-0 |
| MF: | 2C18H15P.Cu.BH4 |
| MW: | 602.97 |
| EINECS: | 240-951-0 |
| Product Categories: | Cu;B (Classes of Boron Compounds);Classes of Metal Compounds;Cu (Copper) Compounds;Reduction;Synthetic Organic Chemistry;Tetrahydroborates;Transition Metal Compounds |
| Mol File: | 16903-61-0.mol |
| Bis-(triphenylphosphino)-cuprous borohydride Chemical Properties |
| Melting point | 164 °C (dec.)(lit.) |
| storage temp. | Store below +30°C. |
| form | powder to crystal |
| color | White to Almost white |
| Sensitive | Moisture Sensitive |
| Exposure limits | ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 |
| CAS DataBase Reference | 16903-61-0(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38-15 |
| Safety Statements | 26-60-43-37-7/8 |
| RIDADR | 2813 |
| WGK Germany | 3 |
| F | 9-21 |
| HazardClass | 4.3 |
| PackingGroup | III |
| HS Code | 29319019 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| Bis-(triphenylphosphino)-cuprous borohydride Usage And Synthesis |
| Uses | Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0) is an organometallic catalyst used in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. Bis(triphenylphosphine)copper tetrahydroborate is also used in the preparation of tungsten, ruthenium and copper cluster complexes. |
| Bis-(triphenylphosphino)-cuprous borohydride Preparation Products And Raw materials |
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