ALUMINUM ETHOXIDE

ALUMINUM ETHOXIDE
  • CAS No.:555-75-9
Other grades of this product :
ALUMINUM ETHOXIDE Basic information
Product Name:ALUMINUM ETHOXIDE
Synonyms:triethoxyaluminum;Aluminumethoxide,99%;ethanol,aluminumsalt;ethylalcohol,aluminumsalt;ALUMINUM TRIETHYLATE;Aliuminum ethylate;Tris(ethoxy) aluminum;Aluminium triethoxide,99%
CAS:555-75-9
MF:C6H15AlO3
MW:162.16
EINECS:209-105-8
Product Categories:metal alkoxide;Al (Alminum) Compounds;Classes of Metal Compounds;Typical Metal Compounds
Mol File:555-75-9.mol
ALUMINUM ETHOXIDE Chemical Properties
Melting point 154-159 °C (lit.)
Boiling point 320 °C
density 1,142 g/cm3
vapor pressure 0.004Pa at 25℃
Fp 210°C/10mm
storage temp. Store below +30°C.
form Powder/Chunks
color White
Specific Gravity1.142
Water Solubility Soluble in hot xylene, cholorobenzene. Reacts with water.
Hydrolytic Sensitivity8: reacts rapidly with moisture, water, protic solvents
Sensitive Moisture Sensitive
Merck 14,338
BRN 3678970
CAS DataBase Reference555-75-9(CAS DataBase Reference)
EPA Substance Registry SystemAluminum ethoxide (555-75-9)
Safety Information
Hazard Codes F,C
Risk Statements 11-15-34
Safety Statements 8-16-26-36/37/39-43-45
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
3-10-23
TSCA Yes
HS Code 2905 19 00
HazardClass 4.1
PackingGroup II
Hazardous Substances Data555-75-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
ALUMINUM ETHOXIDE Usage And Synthesis
Chemical Propertiesliquid that slowly solidifies to a white powder(s); sensitive to moisture; prepared from a reaction of Al with ethanol in the presence of catalytic amounts of I2 and HgCl2; used as a polymerization catalyst and to reduce aldehydes and ketones [MER06] [STR93] [HAW93]
UsesIn the reduction of aldehydes and ketones; as catalyst for polymerizations.
UsesAluminum ethoxide is mainly used in industrial settings. It is used as a reducing agent for aldehyde, ketones, polymerization catalyst. Used in the sol-gel process preparation of high purity aluminum sesquioxide. It also used as a reducing reagent, for carbonyl compounds that restore to alcohol.
Flammability and ExplosibilityFlammable
Purification MethodsCrystallise it from CS2 [m 139o, CS2 complex] and distil it in a vacuum. The molecular weight corresponds to [Al(OEt)3]4 [Robinson & Peak J Phys Chem 39 1127 1935, Vilani & Nord J Am Chem Soc 69 2605 1947]. [Beilstein 1 H 313, 1 I 158, 1 II 3008, 1 III 1284, 1 IV 1289.]
ALUMINUM ETHOXIDE Preparation Products And Raw materials
Preparation ProductsButyl butyrate

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