alpha-L-Rhamnose

alpha-L-Rhamnose
  • CAS No.:3615-41-6
Other grades of this product :
alpha-L-Rhamnose Basic information
Product Name:alpha-L-Rhamnose
Synonyms:6-Deoxyhexopyranose;6-deoxy-l-mannos;6-Deoxymannose;Isoducitol;L-Mannopyranose, 6-deoxy-;Locaose;Mannose, 6-deoxy-;Rhamnopyranose
CAS:3615-41-6
MF:C6H12O5
MW:164.16
EINECS:222-793-4
Product Categories:FINE Chemical & INTERMEDIATES;Biochemistry;Deoxysugars;Rhamnose;Sugars;Dextrins、Sugar & Carbohydrates;Plant extracts;Herb extract;bc0001
Mol File:3615-41-6.mol
alpha-L-Rhamnose Chemical Properties
Melting point 91-95°C
Boiling point 251.61°C (rough estimate)
density 1.3058 (rough estimate)
refractive index 1.6400 (estimate)
FEMA 3730 | L-RHAMNOSE
storage temp. 2-8°C
pka12.50±0.20(Predicted)
Water Solubility 521.5g/L(40 ºC)
Merck 8172
LogP-2.17 at 25℃
CAS DataBase Reference3615-41-6(CAS DataBase Reference)
NIST Chemistry ReferenceL-Mannose, 6-deoxy-(3615-41-6)
EPA Substance Registry SystemL-Mannose, 6-deoxy- (3615-41-6)
Safety Information
MSDS Information
alpha-L-Rhamnose Usage And Synthesis
Chemical PropertiesWhite crystals. For equilibrium mixture optical rotation is +9.18 degrees. Very soluble in water and in methanol; soluble in absolute alcohol.
Chemical PropertiesL-Rhamnose has no odor, but has a very sweet taste.
UsesSynthetic sweetener research.
DefinitionChEBI: The acyclic form of L-rhamnose.
Flammability and ExplosibilityNotclassified
Purification MethodsCrystallise the rhamnose from H2O or EtOH. It crystallises easily as the monohydrate by evaporating a solution in MeOH (90%) and H2O (10%). It is also purified by dissolving in a small volume of EtOH, adding a few drops of H2O and cooling. 1H NMR in D2O at 44o contains 60% -pyranose and 40% -pyranose forms [Angyal Adv Carbohydr Chem 42 15 1984.] [Smith J Chem Soc 1035 1940, McGeachin & Beevers Acta Cryst 10 227,230 197, Beilstein 1 IV 4261.]
alpha-L-Rhamnose Preparation Products And Raw materials
Raw materialsIsorhamnetin-->RUSCOGENIN-->D(+)-Glucose-->D-Galactose
Preparation ProductsC10836-->D-(+)-FUCOSE-->METHYL ALPHA-L-RHAMNOPYRANOSIDE-->L-RHAMNOSE DIETHYLMERCAPTAL-->L-Arabinose-->D(+)-Xylose

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