2-Carboxyethyl acrylate

2-Carboxyethyl acrylate
  • CAS No.:24615-84-7
Other grades of this product :
2-Carboxyethyl acrylate Basic information
Product Name:2-Carboxyethyl acrylate
Synonyms:.beta.-Carboxyethylacrylate;2-CARBOXYETHYL ACRYLATE;2-Carboxyethyl acrylate oligomers, n=0-3;β-Carboxyethyl acrylate;2-carboxyethyl acrylate oligomers;3-acryloyloxypropionic acid;B-Carboxyethyl acrylate;RARECHEM AL BO 0311
CAS:24615-84-7
MF:C6H8O4
MW:144.13
EINECS:246-359-9
Product Categories:monomer;AcrylateCarbonyl Compounds;Acrylic Monomers;C6 to C7;Esters;Monomers;Acrylate
Mol File:24615-84-7.mol
2-Carboxyethyl acrylate Chemical Properties
Boiling point 103 °C/19 mmHg (lit.)
density 1.214 g/mL at 25 °C (lit.)
refractive index n20/D 1.457(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility H2O: soluble
pka3.95±0.10(Predicted)
PH2.95 (10wt. % in H2O)
Merck 13,132
EPA Substance Registry SystemHydracrylic acid acrylate (24615-84-7)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-36/37/38
Safety Statements 23-26-36/37/39-45-36
RIDADR UN 3265 8/PG 2
WGK Germany 3
RTECS UD3325250
HS Code 29161290
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Carboxyethyl acrylate Usage And Synthesis
Chemical PropertiesColorless to light yellow viscid liquid
Uses2-Carboxyethyl Acrylate is used in the preparation of DNase enzyme derivatives that act as potent preventative material of bacterial adhesion and biofilm formation in biomaterials.
Application2-Carboxyethyl acrylate can be polymerized in solution or emulsion to produce acrylic, vinyl acrylic, or styrene acrylic polymers, which are distinguished by their low glass transition temperatures (<30°C) as homopolymers. Greater elasticity, as well as improved adhesion.
PreparationSynthesis of 1-ethoxyethyl acrylate (EEA) and protected 2-carboxyethyl acrylate (proCEA)EEA and proCEA were synthesized following a previously published procedure and distilled prior to use. For the synthesis of proCEA (Figure 1), phosphoric acid (109 mg, 1.11 mmol) was weighed into a dry round bottom flask in a glovebox and then taken outside the glovebox, taking care that the phosphoric acid stayed dry. 2-Carboxyethyl acrylate (80 g, 555 mmol) and ethyl vinyl ether (48 g, 666 mmol) were added and the reaction was stirred for two days at room temperature. Hydrotalcite (Mg6Al2(OH)16CO3·4H2O, ~1 g) was added, stirred for one hour and filtered off. Excess ethyl vinyl ether was removed under reduced pressure and the product was distilled under reduced pressure (80 °C, 1.3 mbar).Figure 1 Synthesis of proCEA
HazardA severe skin irritant.
2-Carboxyethyl acrylate Preparation Products And Raw materials

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