2-Fluorotoluene

CAS No.：95-52-3

Other grades of this product :

2-Fluorotoluene Basic information

Product Name:	2-Fluorotoluene
Synonyms:	1-Fluor-2-methylbenzol;1-fluoro-2-methyl-benzen;1-Fluoro-2-methylbenzene;1-fluoro-2-methyl-benzene;1-Methyl-2-fluorobenzene;2-fluoromethylbenzene;2-FLUOROTOLUENE;Benzene,1-fluoro-2-methyl-
CAS:	95-52-3
MF:	C7H7F
MW:	110.13
EINECS:	202-428-5
Product Categories:	Aryl Fluorinated Building Blocks;Building Blocks;C7-C8;Chemical Synthesis;Fluorinated Building Blocks;Halogenated Hydrocarbons;Aromatic Hydrocarbons (substituted) & Derivatives;Organics;Aryl;organofluorine compounds;Organic Building Blocks;Organic Fluorinated Building Blocks;Other Fluorinated Organic Building Blocks;alkyl Fluorine;C7;Halogenated Hydrocarbons
Mol File:	95-52-3.mol

2-Fluorotoluene Chemical Properties

Melting point	-62 °C (lit.)
Boiling point	113-114 °C (lit.)
density	1.001 g/mL at 25 °C (lit.)
vapor density	3.8 (vs air)
vapor pressure	21 mm Hg ( 20 °C)
refractive index	n20/D 1.473(lit.)
Fp	55 °F
storage temp.	Store below +30°C.
form	Liquid
Specific Gravity	1.001
color	Clear colorless to slightly yellow
explosive limit	1.3%(V)
Water Solubility	immiscible
Merck	14,4180
BRN	1853362
LogP	2.73-2.74
CAS DataBase Reference	95-52-3(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-fluoro-2-methyl-(95-52-3)
EPA Substance Registry System	o-Fluorotoluene (95-52-3)

Safety Information

Hazard Codes	F,Xi
Risk Statements	11-36/37/38
Safety Statements	16-26-33-36-37/39
RIDADR	UN 2388 3/PG 2
WGK Germany	3
RTECS	XT2579000
Hazard Note	Flammable/Irritant
TSCA	Yes
HazardClass	3
PackingGroup	II
HS Code	29036990
Toxicity	LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS Information

Provider	Language
2-Fluorotoluene	English
SigmaAldrich	English
ACROS	English
ALFA	English

2-Fluorotoluene Usage And Synthesis

Chemical Properties	clear colorless to slightly yellow liquid
Uses	It is employed in organic synthesis.
General Description	A colorless liquid with an aromatic odor. May sink or float on water.
Air & Water Reactions	Highly flammable. Insoluble in water.
Reactivity Profile	2-Fluorotoluene is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999].
Health Hazard	Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects.
Purification Methods	Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.]

2-Fluorotoluene Preparation Products And Raw materials

Raw materials	2-Chlorotoluene-->3-Fluorotoluene
Preparation Products	2-Fluorobenzoyl chloride-->2-Fluoro-5-nitrotoluene-->2-FLUORO-3-NITROBENZOIC ACID-->alpha-Chloro-o-fluorotoluene-->Cyclopropyl 2-fluorobenzyl ketone-->4-acetyl-2-methylbenzoic acid-->2-TERT-BUTYL-1H-INDOLE-->7-METHYL (1H)INDAZOLE-->2-Fluorostyrene-->2-METHYLPHENYLBORONIC ACID, PINACOL ESTER-->2-Fluoro-3-methylBenzonitrile-->o-fluorocinnamic acid-->2-Fluoro-5-nitrobenzoic acid-->p-Fluorotoluene

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873