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| 5-Bromopyrimidine Basic information |
| Product Name: | 5-Bromopyrimidine | | Synonyms: | 5-bromo-pyrimidin;PYRIMIDINE, 2-BROMO-;PYRIMIDINE, 5-BROMO-;5-BROMOPYRIMIDINE;5-Bromopyrimidine,98%;Pyrimidine,5-bromo-(6CI,7CI,8CI,9CI);5-BROMOISATINIC ANHYDRIDE;5-BROMOPYRIMIDINE, 99% MIN | | CAS: | 4595-59-9 | | MF: | C4H3BrN2 | | MW: | 158.98 | | EINECS: | 224-992-1 | | Product Categories: | Halides;Pyrazines, Pyrimidines & Pyridazines;Aromatics Compounds;Aromatics;Heterocycles;Pyrazines, Pyrimidines & Pyridazines;HALIDE;Building Blocks;Halogenated Heterocycles;Heterocyclic Building Blocks;Pyrimidines;PyrimidinesHeterocyclic Building Blocks;Pyrimidine;Heterocycle-Pyrimidine series;Pyridines, Pyrimidines, Purines and Pteredines;bc0001 | | Mol File: | 4595-59-9.mol |
| 5-Bromopyrimidine Chemical Properties |
| Hazard Codes | Xi | | Risk Statements | 36/37/38-36/38 | | Safety Statements | 26-36-37/39 | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | T | | HazardClass | IRRITANT, KEEP COLD | | HS Code | 29335990 |
| 5-Bromopyrimidine Usage And Synthesis |
| Chemical Properties | yellow solid crystalline, insoluble in water, soluble in organic solvents such as benzene and toluene. | | Uses | 5-Bromopyrimidine was used in the synthesis of N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction, (5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocol. | | Uses | 5-Bromopyrimidine was used in the synthesis of:N-heteroaryl substituted 9-arylcarbazolyl derivatives via palladium-catalyzed aerobic and ligand-free Suzuki reaction(5-(phenylethynyl)pyrimidine) via microwave assisted organic synthesis (MAOS) Sonogashira protocolIntermediate for the synthesis of plant growth regulator flurprimidol | | Application | 5-Bromopyrimidine is a compound useful in organic synthesis. | | Preparation | 5-Bromopyrimidine is prepared by reacting dibromodifuranone with formamide in the presence of B2O2 catalyst at 180-185°C to obtain the product. | | General Description | Rapid nucleophilic displacement reactions of 5-bromopyrimidine with nucleophiles under microwave irradiation has been studied. 5-Bromopyrimidine undergoes direct metallation with lithuium diisopropylamide to yield 4-lithio-5-bromopyrimidine. |
| 5-Bromopyrimidine Preparation Products And Raw materials |
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