Bis(triphenylphosphine)iminium chloride

Bis(triphenylphosphine)iminium chloride
  • CAS No.:21050-13-5
Other grades of this product :
Bis(triphenylphosphine)iminium chloride Basic information
Product Name:Bis(triphenylphosphine)iminium chloride
Synonyms:HEXAPHENYLDIPHOSPHAZENIUM CHLORIDE;BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IMINIUM CHLORIDE;BIS(TRIPHENYLPHOSPHINE)IMINIUMHLORIDE;PPNCI;PHOSPHORUS(1+), TRIPHENYL(P,P,P-TRIPHENYLPHOSPHINEIMIDATO-KN)-, CHLORIDE, (T-4)-;bis((triphenyl-$l^{5}-phosphanylidene)azanium) dichloride;triphenyl-(triphenylphosphoranylideneamino)phosphonium chloride
CAS:21050-13-5
MF:C36H30ClNP2
MW:574.04
EINECS:244-170-6
Product Categories:Furans ,Coumarins;organophosphine ligand;Pharmaceutical Intermediates
Mol File:21050-13-5.mol
Bis(triphenylphosphine)iminium chloride Chemical Properties
Melting point 270-272 °C(lit.)
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Powder
color white
Water Solubility Moderately soluble in water.
BRN 4097979
CAS DataBase Reference21050-13-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20
Safety Statements 26-36-38-36/37/39-22
WGK Germany 3
10
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Bis(triphenylphosphine)iminium chloride Usage And Synthesis
Usessuzuki reaction
UsesCo-catalyst used with a chiral Cobalt-salen complex for the asymmetric addition of carbon dioxide to propylene oxide. Also used in the preparation of 5-Hydroxy-clethodim Sulfoxide.
UsesBis(triphenylphosphoranylidene)ammonium chloride was used in two-phase titration and electrochemistry, done for physiochemical characterization of sildenafil. It was also used in cyclic voltammetry reactions, used to study ion transfer (IT) and electron transfer (ET), at a liquid-liquid interface supported on a metallic electrode.
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