(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL

(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL
  • CAS No.:42177-25-3
Other grades of this product :
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Basic information
Product Name:(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL
Synonyms:(r)-(+)-α-methyl-1-naphthalenemethanol;R-(-)-1-(1-Napthalenyl)ethanol;R-(-)-1-(1-naphthalenyl)ethanol;(R)-(+)-1-(1-NAPHTHYL)ETHANOL;(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL;(1R)-1-(1-naphthyl)ethan;(1R)-1-(1-naphthyl)ethanol;1-Naphthalenemethanol, α-methyl-, (αR)-
CAS:42177-25-3
MF:C12H12O
MW:172.22
EINECS:
Product Categories:
Mol File:42177-25-3.mol
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Chemical Properties
Melting point 47-49 °C(lit.)
alpha 78 º (C=1 IN MEOH)
Boiling point 316.0±11.0 °C(Predicted)
density 1.113±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka14.29±0.20(Predicted)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
HS Code 29062990
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Usage And Synthesis
Chemical PropertiesWhite solid
Uses(R)?-?1-?(Naphthalen-?1-?yl)?ethanol is a coupling reagent used in the synthesis of ferrocene aminophosphoxazoline ligands.
Purification MethodsPurify the alcohol by recrystallisation from Et2O/pet ether, Et2O, hexane [Balfe et al. J Chem Soc 797 1946, IR, NMR: Theisen & Heathcock J Org Chem 53 2374 1988, see also Fredga et al. Acta Chem Scand 11 1609 1957]. The RS-alcohol [57605-95-5] has m 63-65o, 65-66o from hexane. [Beilstein 6 III 3034, 6 IV 4346.]
(R)-(+)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Preparation Products And Raw materials

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