(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

CAS No.：169689-05-8

Other grades of this product :

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Basic information

Reaction

Product Name:	(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:	(1S,2S)-(-)-1,2-TROST LIGAND;(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl);(S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand;1S,2S- DHAC-Phenyl Trost Ligand;95% (S,S)-DACH-Phenyl Trost Ligand
CAS:	169689-05-8
MF:	C44H40N2O2P2
MW:	690.76
EINECS:
Product Categories:	Chiral Nitrogen;DACH&Trost Series
Mol File:	169689-05-8.mol

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties

Melting point	134-136°C
alpha	-134o (C=1 IN METHANOL)
Boiling point	817.0±65.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	13.35±0.40(Predicted)
form	Powder
color	white to off-white
optical activity	[α]20/D -134°, c = 1 in methanol

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

MSDS Information

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis

Reaction	The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.
Uses	Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

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