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| Benzyl 2-bromoacetate Basic information |
| Benzyl 2-bromoacetate Chemical Properties |
| Melting point | 199-201 °C(Solv: water (7732-18-5)) | | Boiling point | 166-170 °C22 mm Hg(lit.) | | density | 1.446 g/mL at 25 °C(lit.) | | refractive index | n20/D 1.544(lit.) | | Fp | >230 °F | | storage temp. | Keep in dark place,Sealed in dry,Room Temperature | | solubility | Chloroform, Methanol | | form | Liquid | | Specific Gravity | 1.446 | | color | Clear colorless to light yellow | | Water Solubility | Not miscible or difficult to mix in water. | | BRN | 973658 | | CAS DataBase Reference | 5437-45-6(CAS DataBase Reference) | | NIST Chemistry Reference | Benzyl 2-bromoacetate(5437-45-6) | | EPA Substance Registry System | Benzyl bromoacetate (5437-45-6) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-37/39 | | RIDADR | 2810 | | WGK Germany | 3 | | RTECS | AF5957215 | | F | 19 | | HS Code | 29159080 |
| Benzyl 2-bromoacetate Usage And Synthesis |
| Chemical Properties | Colorless to light yellow liqui | | Uses | It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid. | | Purification Methods | Dilute the ester with Et2O, wash it with 10% aqueous NaHCO3, H2O, dry (MgSO4) and fractionate it using a Fenske (glass helices packing) column. [Bergmann & Szinai J Chem Soc 1521 1956, Beilstein 6 IV 2265.] LACHRYMATORY. |
| Benzyl 2-bromoacetate Preparation Products And Raw materials |
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