2-Amino-4-methoxy-6-methylpyrimidine

2-Amino-4-methoxy-6-methylpyrimidine
  • CAS No.:7749-47-5
Other grades of this product :
2-Amino-4-methoxy-6-methylpyrimidine Basic information
Product Name:2-Amino-4-methoxy-6-methylpyrimidine
Synonyms:2-Pyrimidinamine, 4-methoxy-6-methyl- (9CI);2-Amino-4-methoxy-6-methylpyrimidine, 99+%;4-Methoxy-6-methylpyrimidine-2-amine;4-Methyl-6-methoxypyrimidine-2-amine;2-AMINO-4-METHOXY-6-METHYLPYRIMIDINE, 98 %;4-METHOXY-6-METHYL-2-PYRIMIDINAMINE;4-Methoxy-6-methylpyrimidin-2-amine;TIMTEC-BB SBB006744
CAS:7749-47-5
MF:C6H9N3O
MW:139.16
EINECS:
Product Categories:Heterocycle-Pyrimidine series;PYRIMIDINE;FINE Chemical & INTERMEDIATES;Pyridines, Pyrimidines, Purines and Pteredines;Building Blocks;Heterocyclic Building Blocks;Pyrimidines
Mol File:7749-47-5.mol
2-Amino-4-methoxy-6-methylpyrimidine Chemical Properties
Melting point 156-158 °C (lit.)
Boiling point 255.11°C (rough estimate)
density 1.2081 (rough estimate)
refractive index 1.6500 (estimate)
solubility methanol: soluble1%, clear to very slightly hazy, colorless to yellow
form powder to crystal
color White to Almost white
BRN 121733
CAS DataBase Reference7749-47-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-21/22
Safety Statements 26-36-37/39
WGK Germany 3
8
Hazard Note Irritant
HS Code 29335990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
2-Amino-4-methoxy-6-methylpyrimidine Usage And Synthesis
Chemical Propertieswhite to pinkish or light beige
Uses2-Amino-4-methoxy-6-methylpyrimidine may be employed as nucleophile to investigate the regioselective introduction of some nucleophiles at the secondary position of Baylis-Hillman adducts. It may be used in the preparation of 2-amino-4-methoxy-6-methylpyrimidin-1-ium picrate.
General Description2-Amino-4-methoxy-6-methylpyrimidine (AMMP) is a pyrimidine derivative.It acts as electron donor and forms charge transfer complexes with iodine (σ-electron acceptor). The FTIR and FT-Raman spectra of 2-amino-4-methoxy-6-methylpyrimidine have been recorded to evaluate the energy, structural and thermodynamical parameters. Molecules of AMMP exhibit space group of Pnma and are joined by two N-H…N hydrogen bonds.
Purification MethodsRecrystallise it from H2O. The picrate has m 220-221o(dec). [Baker et al. J Am pKEst ~ Chem Soc 69 3072, 3075 1947, Sirakawa et al. Yakugaku Zasshi 73 598 1953, Backer & Grevenstuk Recl Trav Chim, Pays-Bas 61 291 1942, Beilstein 25 III/IV 3385.]
2-Amino-4-methoxy-6-methylpyrimidine Preparation Products And Raw materials

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