4-Bromophenoxybenzene

4-Bromophenoxybenzene
  • CAS No.:101-55-3
Other grades of this product :
4-Bromophenoxybenzene Basic information
Product Name:4-Bromophenoxybenzene
Synonyms:4-BROMOPHENYL PHENYL ETHER;4-bromophenoxybenzene;4-BROMODIPHENYL ETHER;4-BROMODIPHENYL OXIDE;p-phenoxybromobenzene;p-Phenoxyphenyl bromide;1-Bromo-4-phenoxybenzene;P-BROMODIPHENYL ETHER
CAS:101-55-3
MF:C12H9BrO
MW:249.1
EINECS:202-952-4
Product Categories:Alcohol& Phenol& Ethers;API intermediates;Biphenyl & Diphenyl ether
Mol File:101-55-3.mol
4-Bromophenoxybenzene Chemical Properties
Melting point 18 °C (lit.)
Boiling point 305 °C (lit.)
density 1.423 g/mL at 25 °C (lit.)
vapor pressure 1.94 x 10-3 mmHg at 25 °C (subcooled liquid, Tittlemier et al., 2002)
refractive index n20/D 1.607(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Soluble in ether (Weast, 1986) and many other solvents including 1,4-dioxane, benzene, and toluene.
form Liquid
color Colorless to Almost colorless
BRN 1308972
Henry's Law Constant2.27 at 25 °C (integrated gas-stripping method, GC, Lau et al., 2006)
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKeyJDUYPUMQALQRCN-UHFFFAOYSA-N
CAS DataBase Reference101-55-3(CAS DataBase Reference)
NIST Chemistry ReferenceBenzene, 1-bromo-4-phenoxy-(101-55-3)
EPA Substance Registry Systemp-Bromophenyl phenyl ether (101-55-3)
Safety Information
Hazard Codes N,Xn,F
Risk Statements 50/53-67-65-38-11-43-41-22
Safety Statements 60-61-62-36/37/39-26-33-29-16-9
RIDADR UN 3082 9/PG 3
WGK Germany 3
TSCA Yes
HazardClass 9
PackingGroup III
HS Code 29093090
Hazardous Substances Data101-55-3(Hazardous Substances Data)
ToxicityLC50 (24-h) for Daphnia magna 0.46 mg/L (LeBlanc, 1980).
MSDS Information
ProviderLanguage
4-Bromophenoxybenzene English
SigmaAldrich English
ALFA English
4-Bromophenoxybenzene Usage And Synthesis
Chemical Propertieslight yellow liquid
DefinitionChEBI: An aromatic ether that is diphenyl ether substituted at position 4 by a bromo group.
General DescriptionLiquid. Freezing point 18°C. Density 1.423 g / cm3. Insoluble or slightly soluble in water.
Air & Water ReactionsInsoluble in water.
Reactivity Profile4-Bromophenoxybenzene oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979 p.151-154, 164].
Fire HazardCombustible.
Environmental fateBiological. Using settled domestic wastewater inoculum, 4-bromophenyl phenyl ether (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981). Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 303, 112, 41, and 15 mg/g, respectively (Dobbs and Cohen, 1980).

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