Holmium chloride

Holmium chloride
  • CAS No.:10138-62-2
Other grades of this product :
Holmium chloride Basic information
Product Name:Holmium chloride
Synonyms:HOLMIUM(III) CHLORIDE;HOLMIUM(III) CHLORIDE HYDRATE;HOLMIUM CHLORIDE;HOLMIUM CHLORIDE HEXAHYDRATE;HOLMIUM CHLORIDE, HYDROUS;HOLMIUM TRICHLORIDE;HoCl3;Holmium chloride (HoCl3)
CAS:10138-62-2
MF:Cl3Ho
MW:271.29
EINECS:233-387-1
Product Categories:metal halide;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Holmium Salts;HolmiumMetal and Ceramic Science;Inorganics;Salts;Other Metal
Mol File:10138-62-2.mol
Holmium chloride Chemical Properties
Melting point 718 °C(lit.)
Boiling point 1500°C
density 3,7 g/cm3
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form powder
color Off-white to pink
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 14,4727
Stability:hygroscopic
CAS DataBase Reference10138-62-2(CAS DataBase Reference)
EPA Substance Registry SystemHolmium chloride (HoCl3) (10138-62-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
RTECS MS7350000
TSCA Yes
HS Code 28469000
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Holmium chloride Usage And Synthesis
Chemical PropertiesYellow monoclinic crystals; hygroscopic; density 3.7 g/cm3 ; melts at 718°C; vaporizes at 1,500°C; readily dissolves in water.
Physical propertiesYellow monoclinic crystals; hygroscopic; density 3.7 g/cm3; melts at 718°C;vaporizes at 1,500°C; readily dissolves in water.
UsesHolmium(III) chloride has many application in the field of nuclear industry, lasers research applications. It is also employed in calibration of optical spectrophotometers.
UsesHolmium chloride is an intermediate for preparing holmium metal.
PreparationHolmium chloride is obtained from rare-earth minerals. Recovery steps are discussed above (see Holmium). The rare-earth mineral is cracked by acid attack by heating with hydrochloric acid. The water-soluble chloride salt is filtered and separated from insoluble residues. The hydrated chloride salt is heated at 350°C in a current of hydrogen chloride to yield anhydrous HoCl3 . Heating in air in the absence of hydrogen chloride yields holmium oxychloride, HoOCl. Holmium chloride may be purified by distillation or vacuum sublimation. Holmium chloride also can be prepared by heating holmium oxide with ammonium chloride: Ho2O3 + 6NH4Cl-->2HoCl3 + 6NH3 + 3H2O
Holmium chloride Preparation Products And Raw materials

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