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| (DHQD)2PHAL Basic information |
| Product Name: | (DHQD)2PHAL | | Synonyms: | SHARPLESS CATALYST;(DHQD)2PHAL;HYDROQUINIDINE 1,4-PHTHALAZINEDIYL DIETHER;DHQD)2 PHAL;(DHQD)2 PHAL, 95+%;HYDROQUININE-1,4-PHTHALOZINEDIYL DIETHER;Hydroquinidine 1,4-phthalazinediyl diether((DHQD)2PHAL);(DHQD)2PHAL,Hydroquinidine 1,4-phthalazinediyl diether | | CAS: | 140853-10-7 | | MF: | C48H54N6O4 | | MW: | 778.98 | | EINECS: | 1308068-626-2 | | Product Categories: | | Mol File: | 140853-10-7.mol |
| (DHQD)2PHAL Chemical Properties |
| Melting point | 160 °C (dec.)(lit.) | | alpha | -262 º (C=1.2 IN MEOH) | | density | 1.3 | | storage temp. | Inert atmosphere,Room Temperature | | solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly) | | pka | 9.61±0.70(Predicted) | | form | Solid | | color | White to Pale Yellow | | optical activity | [α]22/D 262°, c = 1.2 in methanol | | BRN | 5475678 | | InChIKey | YUCBLVFHJWOYDN-SOBQURILSA-N | | CAS DataBase Reference | 140853-10-7(CAS DataBase Reference) |
| Safety Statements | 22-24/25 | | WGK Germany | 3 | | F | 9 | | HS Code | 29392000 |
| (DHQD)2PHAL Usage And Synthesis |
| Uses | (DHQD)2PHAL is a monomeric cinchona alkaloid dimer used as a catalyst for asymmetric halogenations. | | Uses | (DHQD)2PHAL may be used as ligand for:- Osmium trioxide catalyzed asymmetric dihydroxylation of olefins.
- Palladium catalyzed Suzuki-Miyaura coupling of aryl/heteroaryl halides with aryl boronic acids in aqueous medium and in the absence of phosphine/organic solvent.
- Copper(I)-catalyzed azide-alkyne cycloaddition reaction to synthesize 1,2,3-triazoles in water.
| | General Description | (DHQD)2PHAL is a modified cinchona alkaloid derivative mainly used as a ligand for enantioselective catalysis. |
| (DHQD)2PHAL Preparation Products And Raw materials |
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