Cyclopropyl phenyl ketone

Cyclopropyl phenyl ketone
  • CAS No.:3481-02-5
Other grades of this product :
Cyclopropyl phenyl ketone Basic information
Product Name:Cyclopropyl phenyl ketone
Synonyms:Methanone,cyclopropylphenyl-;Phenyl cyclopropyl ketone;BENZOYLCYCLOPROPANE;CYCLOPROPYL PHENYL KETONE;CYCLOPROPYL-PHENYL-METHANONE;Cyclopropylphenylketone,97%;Cyclopropyl phenyl k;Cyclopropyl phenyl ketone 98%
CAS:3481-02-5
MF:C10H10O
MW:146.19
EINECS:222-458-2
Product Categories:Cyclopropanes;Simple 3-Membered Ring Compounds
Mol File:3481-02-5.mol
Cyclopropyl phenyl ketone Chemical Properties
Melting point 7-9 °C(lit.)
Boiling point 121-123 °C15 mm Hg(lit.)
density 1.058 g/mL at 25 °C(lit.)
vapor density 5 (vs air)
refractive index n20/D 1.553(lit.)
Fp 195 °F
storage temp. Sealed in dry,2-8°C
form clear liquid
color Colorless to Light yellow
Water Solubility Insoluble in water.
BRN 1860145
CAS DataBase Reference3481-02-5(CAS DataBase Reference)
NIST Chemistry ReferenceCyclopropyl phenyl ketone(3481-02-5)
Safety Information
Safety Statements 23-24/25
WGK Germany 3
HS Code 2914390090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Cyclopropyl phenyl ketone Usage And Synthesis
Chemical PropertiesCLEAR COLOURLESS TO LIGHT YELLOW LIQUID
UsesCyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
UsesCyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formationfrom cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
Synthesis Reference(s)The Journal of Organic Chemistry, 45, p. 2921, 1980 DOI: 10.1021/jo01302a038Tetrahedron Letters, 16, p. 4389, 1975 DOI: 10.1016/S0040-4039(00)91132-8

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