(Trimethylsilyl)methylamine

(Trimethylsilyl)methylamine
  • CAS No.:18166-02-4
Other grades of this product :
(Trimethylsilyl)methylamine Basic information
Product Name:(Trimethylsilyl)methylamine
Synonyms:(AMINOMETHYL)TRIMETHYLSILANE;(TRIMETHYLSILYL)METHYLAMINE;2-AMINOMETHYLTRIMETHYLSILANE;Methylamine, 1-(trimethylsilyl)-,;1-(trimethylsilyl)methylamine;Aminomethyltrimethylsilane**CUSTOMSYNTHESISPLEASEASK**;AMTMS;Trimethylsilylmethaneamine
CAS:18166-02-4
MF:C4H13NSi
MW:103.24
EINECS:242-049-2
Product Categories:
Mol File:18166-02-4.mol
(Trimethylsilyl)methylamine Chemical Properties
Melting point <0°C
Boiling point 92-94 °C(lit.)
density 0.771 g/mL at 20 °C(lit.)
refractive index n20/D 1.416
Fp 9°C
storage temp. Keep in dark place,Inert atmosphere,Room temperature
pka10.89±0.10(Predicted)
Specific Gravity0.7697
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
BRN 1731488
CAS DataBase Reference18166-02-4(CAS DataBase Reference)
NIST Chemistry ReferenceTrimethylsilylmethylamine(18166-02-4)
Safety Information
Hazard Codes F,C
Risk Statements 11-34-37
Safety Statements 16-26-36/37/39-45
RIDADR UN 2733 3/PG 2
WGK Germany 3
3-10
TSCA No
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
(Trimethylsilyl)methylamine Usage And Synthesis
Purification MethodsA possible contaminant is hexamethyldisiloxane. It should have two 1H NMR signals in CDCl3; if not, dissolve it in *C6H6, shake it with 15% aqueous KOH, separate, dry (Na2SO4), filter, evaporate and distil it using a still of ca 10 theoretical plates. The water azeotrope has b 83o/735mm; hence it is important to dry the extract well. The hydrochloride has m 198-199o (from MeOH or Me2CO). [Noll et al. J Am Chem Soc 73 3867 1951, Beilstein 4 IV 3878.]
(Trimethylsilyl)methylamine Preparation Products And Raw materials

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