TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN

TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN
  • CAS No.:6089-04-9
Other grades of this product :
TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Basic information
Product Name:TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN
Synonyms:2-(2-Propynyloxy)tetrahydro-2H-pyran;pent-4-ynoic acid;TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN, 9 8%;2-(Propargyloxy)tetrahydropyran;2-Propargyloxane;2-Propynyl 2-pyranyl ether;2-Propynyl tetrahydro-2H-pyran-2-yl ether;3-(2'-Tetrahydropyranyloxy)propyne
CAS:6089-04-9
MF:C8H12O2
MW:140.18
EINECS:228-027-5
Product Categories:API intermediates;Boronic ester;Organoborons;Pyran;Acetylenes;Functionalized Acetylenes;Building Blocks;Heterocyclic Building Blocks;Pyrans;Alphabetic;TA - TE
Mol File:6089-04-9.mol
TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Chemical Properties
Boiling point 63-65 °C9 mm Hg(lit.)
density 0.997 g/mL at 25 °C(lit.)
refractive index n20/D 1.458(lit.)
Fp 139 °F
storage temp. 2-8°C
form Liquid
color Clear colorless to light yellow
Specific Gravity0.997
InChIKeyRNRIMDSCBRDPLC-UHFFFAOYSA-N
CAS DataBase Reference6089-04-9
Safety Information
Hazard Codes Xi,F
Risk Statements 11
Safety Statements 26-27-28-36/37/39-16
RIDADR UN 1993 3/PG 3
WGK Germany 3
HazardClass 3.2
PackingGroup III
HS Code 29329900
MSDS Information
ProviderLanguage
SigmaAldrich English
TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Usage And Synthesis
Chemical PropertiesClear colorless to light yellow liquid
UsesTetrahydro-2-(2-propynyloxy)-2H-pyran was used in preparation of 1,3-dienyl acetal.
Synthesis Reference(s)Chemistry Letters, 6, p. 817, 1977Organic Syntheses, Coll. Vol. 7, p. 334, 1990Synthetic Communications, 19, p. 901, 1989 DOI: 10.1080/00397918908051010
General DescriptionThe anion formed by metalation at the acetylenic carbon reacts with a variety of electrophiles.

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