| 1-Bromo-4-(trifluoromethoxy)benzene Basic information |
| Product Name: | 1-Bromo-4-(trifluoromethoxy)benzene |
| Synonyms: | 4-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUOROANISOLE;4-BROMO(TRIFLUOROMETHOXY)BENZENE;4-(TRIFLUOROMETHOXY)BROMOBENZENE;TIMTEC-BB SBB006606;P-TRIFLUOROMETHOXY BROMOBENZENE;P-BROMOTRIFLUOROMETHOXYBENZENE;Benzene, 1-bromo-4-(trifluoromethoxy)-;1-BROMO-4-(TRIFLUOROMETHOXY)BENZENE |
| CAS: | 407-14-7 |
| MF: | C7H4BrF3O |
| MW: | 241.01 |
| EINECS: | 206-979-2 |
| Product Categories: | Ethers;Organic Building Blocks;Trifluoromethoxybenzene Series;Fluorobenzene;Aromatic Halides (substituted);Oxygen Compounds;Miscellaneous;Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;Fluorine Compounds;Building Blocks for Liquid Crystals;Chalcones, etc. (Building Blocks for Liquid Crystals);Functional Materials;Pharmaceutical Intermediate;Trifluoroanisole series;alkyl bromide;bc0001 |
| Mol File: | 407-14-7.mol |
| 1-Bromo-4-(trifluoromethoxy)benzene Chemical Properties |
| Boiling point | 80 °C50 mm Hg(lit.) |
| density | 1.622 g/mL at 25 °C(lit.) |
| vapor pressure | 20 hPa (55 °C) |
| refractive index | n |
| Fp | 154 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | 11.7mg/l |
| form | Liquid |
| Specific Gravity | 1.64 |
| color | Clear colorless to yellow |
| BRN | 2046332 |
| InChIKey | SEAOBYFQWJFORM-UHFFFAOYSA-N |
| CAS DataBase Reference | 407-14-7(CAS DataBase Reference) |
| NIST Chemistry Reference | P-bromophenyl trifluoromethyl ether(407-14-7) |
| Safety Information |
| Hazard Codes | Xn,N,Xi |
| Risk Statements | 22-36/37/38-43-51/53 |
| Safety Statements | 26-36/37-61-37/39-36 |
| RIDADR | UN 3082 9/PG 3 |
| WGK Germany | 1 |
| HazardClass | IRRITANT |
| HS Code | 29093090 |
| Toxicity | LD50 orally in Rabbit: > 2500 mg/kg |
| MSDS Information |
| Provider | Language |
|---|---|
| 1-Bromo-4-(trifluoromethoxy)benzene | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 1-Bromo-4-(trifluoromethoxy)benzene Usage And Synthesis |
| Chemical Properties | CLEAR COLOURLESS TO YELLOW LIQUID |
| Uses | 1-Bromo-4-(trifluoromethoxy)benzene was used in the synthesis of 4-{[4-[(2-ethylhexyloxy)-6-(4-morpholinylmethyl)-4-trifluoromethyl][1,1-biphenyl]-3-yl]methyl}morpholine. |
| Synthesis Reference(s) | Journal of the American Chemical Society, 109, p. 3708, 1987 DOI: 10.1021/ja00246a030 |
| General Description | 1-Bromo-4-(trifluoromethoxy)benzene on treatment with lithium diisopropylamide (LIDA) at -100°C gives 5-bromo-2-(trifluoromethoxy)phenyllithium and at -75°C it eliminates lithium bromide, thus generating 1,2-dehydro-4-(trifluoromethoxy)benzene. |
| 1-Bromo-4-(trifluoromethoxy)benzene Preparation Products And Raw materials |
| Raw materials | Bromobenzene |
| Preparation Products | 1-Iado-4-(trifluoromethoxy)benzene-->4-(Trifluoromethoxy)benzoic acid-->3-(Trifluoromethoxy)bromobenzene |
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