CERIC SULFATE

CERIC SULFATE
  • CAS No.:13590-82-4
Other grades of this product :
CERIC SULFATE Basic information
Product Name:CERIC SULFATE
Synonyms:cericdisulfate;Cericsulfate,anhydrous;ceriumdisulfate;ceriumsulphate;Sulfuricacid,cerium(4+)salt(2:1);sulfuricacid,cerium(4++)salt(2:1);sulfuricacid,ceriumsalt(2:1);TETRASULFATO-CERIC ACID
CAS:13590-82-4
MF:CeH2O4S
MW:238.19
EINECS:237-029-5
Product Categories:Inorganics
Mol File:13590-82-4.mol
CERIC SULFATE Chemical Properties
density 3.01 g/mL at 25 °C(lit.)
vapor pressure 0.001Pa at 20℃
storage temp. Inert atmosphere,Room Temperature
form Liquid
color Light yellow
Water Solubility Soluble in water and dilute sulfuric acid.
Sensitive Hygroscopic
Merck 14,1990
CAS DataBase Reference13590-82-4(CAS DataBase Reference)
EPA Substance Registry SystemSulfuric acid, cerium(4+) salt (2:1) (13590-82-4)
Safety Information
Hazard Codes Xi,O,C
Risk Statements 8-36/38-36/37/38-35
Safety Statements 26-36-17-45-36/37/39
RIDADR UN 2796 8/PG 2
WGK Germany 3
RTECS WS6960000
TSCA Yes
HazardClass 5.1
PackingGroup III
HS Code 2846100090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
CERIC SULFATE Usage And Synthesis
Chemical Propertiesyellow odourless solid
Physical propertiesWhite crystalline powder; orthogonal crystal system; the tetrahydrate is a yellow-to-orange powder which, on heating at 180°C, loses all molecules of water; density of tetrahydrate 3.91 g/cm3; anhydrous salt decomposes at 350°C forming CeOSO4; soluble in water (decomposes); soluble in dilute H2SO4 and other concentrated mineral acids.
Usescalibrated against sodium oxalate, traceable to NIST SRM
UsesCerium(IV) sulfate is a redox indicator and is used in analytical chemistry for redox titrations. In ionized form, ceric ion acts as a strong oxidizer under acidic conditions. It is also used to prepare spherical-like nanoparticles CeO2, nanoparticles for NO reductions' reactions.
PreparationCerium(IV) sulfate is prepared by heating cerium(IV) oxide, CeO2 with concentrated H2SO4. Also it may be obtained by the reaction of H2SO4 with cerium carbonate: Ce(CO3)2 + 2H2SO4 + H2O → Ce(SO4)2?4H2O + 2CO2.
General Description3S - Safe, Smart, SecureAn intelligent packaging solution protected with originality seal.Reagent information is transferred via RFID from reagent bottle to titrator.3S reagents are compatible only with the Metrohm Omnis titration platform.Please see here SigmaAldrich.com/3S
Flammability and ExplosibilityNotclassified
Safety ProfileExperimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
CERIC SULFATE Preparation Products And Raw materials

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