Diphenylphosphine oxide

Diphenylphosphine oxide
  • CAS No.:4559-70-0
Other grades of this product :
Diphenylphosphine oxide Basic information
Product Name:Diphenylphosphine oxide
Synonyms:Diphenylphosphinoxid;Diphenylphosphonousacid;Diphenylphosphineoxide,97%;Diphenylphosphine oxide 97%;Two phenylphosphate oxygen;Phosphine oxide,diphenyl-;DPPO;HPOPh2
CAS:4559-70-0
MF:C12H11OP
MW:202.19
EINECS:625-671-2
Product Categories:Phosphorus Compounds;Phosphorus Precursors;Pharmaceutical Intermediates;Catalysis and Inorganic Chemistry;Achiral Phosphine;Aryl Phosphine
Mol File:4559-70-0.mol
Diphenylphosphine oxide Chemical Properties
Melting point 56-57 °C(lit.)
Boiling point 102-105°C 0,2mm
refractive index 1.608-1.61
storage temp. Inert atmosphere,Room Temperature
form Crystals
color Yellow to light orange
Water Solubility Slightly soluble in water.
Sensitive Moisture Sensitive
InChIKeyASUOLLHGALPRFK-UHFFFAOYSA-N
CAS DataBase Reference4559-70-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26
WGK Germany 2
HS Code 29319090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Diphenylphosphine oxide Usage And Synthesis
Chemical PropertiesYellow to light orange crystals
Usessuzuki reaction
UsesUsed in the preparation of triarylphosphine oxides, and as asymmetric catalysts, preparation of alkenyldiphenylphosphine oxides, and Horner-Wittig reagents. It is a ligand for Buchwald-Hartwig Cross Coupling Reaction, Hydrophosphonylations and Suzuki-Miyaura Coupling.
Synthesis Reference(s)Journal of the American Chemical Society, 45, p. 165, 1923 DOI: 10.1021/ja01654a024

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