| PHENYLSILANE Basic information |
| Product Name: | PHENYLSILANE |
| Synonyms: | Phenylsilane, 98% 25ML;Phenylsilane, 98% 5ML;Phenylsilane,98%;Phenylsilane≥ 98% (GC);PHENYLSILANE;Benzene, silyl-;Fenylsilan;phenyl-silan |
| CAS: | 694-53-1 |
| MF: | C6H8Si |
| MW: | 108.21 |
| EINECS: | 211-772-5 |
| Product Categories: | Silane compounds;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Synthetic Organic Chemistry;Organometallic Reagents;Organosilicon;Others |
| Mol File: | 694-53-1.mol |
| PHENYLSILANE Chemical Properties |
| Melting point | -64 to -68°C |
| Boiling point | 120 °C (lit.) |
| density | 0.877 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 45 °F |
| storage temp. | Flammables area |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.868 |
| Water Solubility | Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents. |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 2935169 |
| InChIKey | PARWUHTVGZSQPD-UHFFFAOYSA-N |
| CAS DataBase Reference | 694-53-1(CAS DataBase Reference) |
| EPA Substance Registry System | Silane, phenyl- (694-53-1) |
| Safety Information |
| Hazard Codes | F,Xn |
| Risk Statements | 11-14/15-20/22-36/37/38 |
| Safety Statements | 16-43 |
| RIDADR | UN 3399 4.3/PG 2 |
| WGK Germany | 1 |
| RTECS | VV4825000 |
| F | 10-21 |
| TSCA | Yes |
| HazardClass | 4.3 |
| PackingGroup | II |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| PHENYLSILANE Usage And Synthesis |
| Chemical Properties | clear colorless liquid |
| Uses | phenylsilane is used as a pharmaceutical intermediate. |
| Uses | Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis. |
| Application | Employed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0). |
| PHENYLSILANE Preparation Products And Raw materials |
| Raw materials | Diethyl ether-->Sulfuric acid-->Tetrahydrofuran-->Sodium-->Potassium carbonate-->Lithium Aluminum Hydride-->Magnesium-->Bromobenzene-->Tetrachlorosilane-->Phenyltrichlorosilane-->CHLOROPHENYLSILANE 97 |
| Preparation Products | Diphenylsilane-->1,1,3-trichloropropane-->PHENYLDICHLOROSILANE-->TRIPHENYLETHOXYSILANE |
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