Aluminum borohydride

Aluminum borohydride
  • CAS No.:16962-07-5
Other grades of this product :
Aluminum borohydride Basic information
Product Name:Aluminum borohydride
Synonyms:Aluminum tetrahydroborate;Aluminum borohydride;ALUMINIUMBOROHYDRIDE;Aluminum borohydride ISO 9001:2015 REACH
CAS:16962-07-5
MF:AlB3H12
MW:71.509818
EINECS:
Product Categories:
Mol File:16962-07-5.mol
Aluminum borohydride Chemical Properties
Melting point -64.5°
Boiling point bp 44.5°; bp119 0°
form flammable liquid
Water Solubility reacts vigorously with H2O and HCl evolving H2 [MER06]
CAS DataBase Reference16962-07-5
EPA Substance Registry SystemBorate(1-), tetrahydro-, aluminum (3:1) (16962-07-5)
Safety Information
RIDADR 2870
HazardClass 4.2
PackingGroup I
MSDS Information
Aluminum borohydride Usage And Synthesis
Chemical PropertiesVolatile, pyrophoric liquid.
UsesReducing agent; preparation of borohydrides of heavy metals; fuel for jet engines and rockets.
General DescriptionA clear, colorless liquid. Slightly denser than water. Contact causes burns to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
Air & Water ReactionsPyrophoric and explodes in oxygen, but only in the the presence of traces of moisture. Reacts vigorously with water, liberating hydrogen [Merck 11th ed. 1989]. Will flame when in contact with water [Ellern 1968 p. 45].
Reactivity ProfileA powerful reducing agent. Reacts rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Incompatible with acids, alcohols, amines, and aldehydes. The borohydride reacts with alkenes and in the presence of oxygen, combustion is initiated even in the absence of moisture. Butene explodes after an induction period, while butadiene explodes immediately. Reaction with dimethylaminoborane or dimethylaminodiborane gives an oily substance which ignites in air and reacts violently with water, [J. Amer. Chem. Soc., 1951, 73, 953].
HazardIgnites spontaneously in air, reacts violently with water.
Health HazardFire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
Fire HazardFlammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
Safety ProfileA poison. Spontaneously flammable in air. Explodes in oxygen with traces of water. Incompatible with alkenes and water. See also ALUMINUM COMPOUNDS and BORON COMPOUNDS.
Aluminum borohydride Preparation Products And Raw materials

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