3-Hydroxybenzyl alcohol

CAS No.：620-24-6

Important Notice

This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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3-Hydroxybenzyl alcohol Basic information

Product Name:	3-Hydroxybenzyl alcohol
Synonyms:	3-(Hydroxymethyl)phenol;Benzyl alcohol, m-hydroxy-;KSD 2405;RARECHEM AL BD 0067;Metaraminol Impurity 3;acetic acid [3,4,6-triacetyloxy-5-[[dimethylamino(oxo)methyl]amino]-2-oxanyl]methyl ester;3-METHYLOLPHENOL;3-Hydroxybenzenemethanol
CAS:	620-24-6
MF:	C7H8O2
MW:	124.14
EINECS:	210-633-6
Product Categories:	Building Blocks;C7 to C8;Benzhydrols, Benzyl & Special Alcohols;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds;Alcohols;C7 to C8;Oxygen Compounds
Mol File:	620-24-6.mol

3-Hydroxybenzyl alcohol Chemical Properties

Melting point	69-72 °C (lit.)
Boiling point	300°C
density	1,16 g/cm³
refractive index	1.5035 (estimate)
Fp	300°C
storage temp.	Inert atmosphere,Room Temperature
solubility	DMSO (Slightly), Methanol (Slightly)
pka	pK1:9.83 (25°C)
form	Crystalline Powder
color	Pink or beige to brown
Water Solubility	soluble
BRN	2041500
CAS DataBase Reference	620-24-6(CAS DataBase Reference)
NIST Chemistry Reference	Benzenemethanol, 3-hydroxy-(620-24-6)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38-41
Safety Statements	26-36/39
WGK Germany	3
RTECS	DA4796700
HS Code	29072900

MSDS Information

Provider	Language
3-Hydroxybenzenemethanol	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-Hydroxybenzyl alcohol Usage And Synthesis

Chemical Properties	pink or beige to brown crystalline powder
Uses	3-Hydroxybenzyl alcohol is used as an intermediate to produce other chemicals like 3-Oxy-1'-acetoxy-1-methyl-benzol.
Definition	ChEBI: A hydroxybenzyl alcohol that is phenol substituted at position C-3 by a hydroxymethyl group.
Synthesis Reference(s)	The Journal of Organic Chemistry, 14, p. 1089, 1949 DOI: 10.1021/jo01158a018Synthesis, p. 365, 1979
Contact allergens	Methylol phenols are sensitizers contained in resins based on phenol and formaldehyde of the resol type. Cross-reactivity is possible with other phenol derivative molecules.
Purification Methods	Crystallise the alcohol from *C6H6 or CHCl3. [Beilstein 6 III 4545, 6 IV 5907.]

3-Hydroxybenzyl alcohol Preparation Products And Raw materials

Raw materials	3-Hydroxybenzaldehyde
Preparation Products	TRIETHYLENE GLYCOL MONOMETHYL ETHER-->3-BENZYLOXYPHENYLACETONITRILE-->PF-04457845-->3-BENZYLOXYBENZYL ALCOHOL-->m-Anisyl alcohol

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