(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX

CAS No.：890090-21-8

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(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Basic information

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Product Name:	(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Synonyms:	Oxazole,2,2'-[(1R)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[4,5-dihydro-4-phenyl-,(4S,4'S)-;(Ra,S,S)-7,7′-bis(4′-phenyloxazol-2-yl)-1,1′-spirobiindane;(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX;(RA,S,S)-SPIROBOX;(4S,4'S)-2,2'-[(1R)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[4,5-DIHYDRO-4-PHENYLOXAZOLE];(R)-7,7'-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2'- 3,3'- tetrahydro-1,1 spirobiindane (Ra,S,S)-SpiroBOX;(R)-7,7-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2,3,3-tetrahydro-1,1-spirobiindane;(4S)-4-phenyl-2-[4'-[(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl]-3,3'-spirobi[1,2-dihydroindene]-4-yl]-4,5-dihydro-1,3-oxazole
CAS:	890090-21-8
MF:	C35H30N2O2
MW:	510.62
EINECS:
Product Categories:
Mol File:	890090-21-8.mol

(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Chemical Properties

Melting point	130-132°C
alpha	+93.0° (c 0.5, CH2Cl2)
Boiling point	712.1±60.0 °C(Predicted)
density	1.29±0.1 g/cm3(Predicted)
pka	4.12±0.70(Predicted)
form	solid
color	white
Sensitive	moisture sensitive

Safety Information

MSDS Information

(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Usage And Synthesis

Reaction

Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into N–H bond of anilines.
Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of phenols.
Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into O–H bond of water.
Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into S–H bonds.
Chiral ligand for copper-catalyzed asymmetric insertions of carbenoids into Si–H bonds.
Chiral ligand used for enantioselective iron-catalyzed intramolecular cyclopropanations.

(R)-7,7Bis[(4S)-(phenyl)oxazol-2-yl)]-2,23,3tetrahydro-1,1spirobiindane, min. 97% (Ra,S,S)-SpiroBOX Preparation Products And Raw materials

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