PHENYL AZIDE

PHENYL AZIDE
  • CAS No.:622-37-7

Important Notice

  1. This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
  2. This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
  3. The purchaser must not use this product, or supply it to another party, for personal consumption, sports or fitness, weight loss, health supplements, food, or animal feed.
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PHENYL AZIDE Basic information
Product Name:PHENYL AZIDE
Synonyms:Azidomethane solution - 0.5M solution intert-butyl methyl ether;Azidobenzene solution ~0.5 M in 2-methyltetrahydrofuran, >=95.0% (HPLC);Azidobenzene;Azido-benzene;Benzene, triazo-;Azidobenzene solution;Phenyl azide solution;diazobenzeneimide
CAS:622-37-7
MF:C6H5N3
MW:119.12
EINECS:210-730-3
Product Categories:Aromatic Azides;Azides;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks
Mol File:622-37-7.mol
PHENYL AZIDE Chemical Properties
Melting point -27.5°C
Boiling point 212.39°C (rough estimate)
density 1.0860
vapor density 73.5 at 22-24 mm
refractive index 1.5589
Fp -12°C
storage temp. -20°C
color Pale-yellow oil
BRN 742248
Safety Information
Hazard Codes F,Xn
Risk Statements 11-19-48/20/21/22-38
Safety Statements 16
RIDADR UN 2398 3 / PGII
WGK Germany 3
MSDS Information
PHENYL AZIDE Usage And Synthesis
UsesPhenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Synthesis Reference(s)Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8
General DescriptionAzidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Safety ProfileExplodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.

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