4-Fluorobenzhydrazide

4-Fluorobenzhydrazide
  • CAS No.:456-06-4
Other grades of this product :
4-Fluorobenzhydrazide Basic information
preparation
Product Name:4-Fluorobenzhydrazide
Synonyms:ASISCHEM R36621;BUTTPARK 35\03-73;4-FLUOROBENZENECARBOHYDRAZIDE;4-FLUOROBENZOYLHYDRAZINE HYDRATE;4-FLUOROBENZHYDRAZIDE;4-FLUOROBENZOHYDRAZIDE HYDRATE;4-FLUOROBENZOIC HYDRAZIDE;4-FLUOROBENZOIC HYDRAZIDE HYDRATE
CAS:456-06-4
MF:C7H7FN2O
MW:154.14
EINECS:207-258-5
Product Categories:Fluorine Compounds;Phenyls & Phenyl-Het;Phenyls & Phenyl-Het;Carbonyl Compounds;Hydrazides;Organic Building Blocks;Fluorobenzene;Benzenes
Mol File:456-06-4.mol
4-Fluorobenzhydrazide Chemical Properties
Melting point 162-166 °C (lit.)
density 1.272±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in methanol.
form Crystalline Powder
pka12.17±0.10(Predicted)
color Orange to light brown
CAS DataBase Reference456-06-4(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
RTECS DH1310000
HazardClass IRRITANT
HS Code 29280000
MSDS Information
ProviderLanguage
SigmaAldrich English
4-Fluorobenzhydrazide Usage And Synthesis
preparationThe synthesized ester (12.5ml) was taken into a round  bottom flask (250ml), 50ml of absolute ethanol &  37.5ml of hydrazine hydrate was added in the flask.  The ester, ethanol & hydrazine hydrate for the synthesis of hydrazide must be in following ratio: Ester: Absolute ethanol: Hydrazine hydrate 1 : 4 : 3  Then round bottom flask was covered with aluminium  foil, placed on hot plate & allowed to stir it for almost  12-15 hrs. As the solid product appeared, reaction  completion was checked by performing TLC using n-hexane, ethyl acetate & TLC cards & observed under  UV lamp. After completion of reaction n-hexane was added.  Solution filtered as needle like crystals appeared.  Allowed it to dry & a shiny off white product was  obtained that was hydrazide & product was calculated  (79%).
Chemical PropertiesWhite solid
UsesUsed in the stnthesis of fluorinated poly (1, 3, 4-oxadiazole-ether-imide). N-(3,5-dinitrobenzoyl)-N?-(4-fluorobenzoyl)-hydrazine with 4-Fluorobenzhydrazide as solvent in NMP.
4-Fluorobenzhydrazide Preparation Products And Raw materials
Raw materialsHydrazine hydrate
Preparation Products1-PHENYLSEMICARBAZIDE

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