(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)

(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
  • CAS No.:132098-59-0
Other grades of this product :
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Basic information
Product Name:(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE)
Synonyms:2,2'-METHYLENEBIS[(4S)-4-PHENYL-2-OXAZOLINE];(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE);(S,S)-2,2''-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) 97+%;4(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE);2,2'-Methylenebis[(4S)-4-phenyl-4,5-dihydro-2-oxazole];Bis((4S)-4,5-dihydro-4-phenyloxazol-2-yl)methane;2,2′-Methylenebis[(4S)-4-phenyl-2-oxazoline],(S,S)-2,2′-Methylenebis(4-phenyl-2-oxazoline);Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane
CAS:132098-59-0
MF:C19H18N2O2
MW:306.36
EINECS:
Product Categories:Chiral Reagent
Mol File:132098-59-0.mol
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Chemical Properties
Boiling point 131-134 °C0.01 mm Hg(lit.)
density 1.28 g/mL at 25 °C(lit.)
refractive index n20/D 1.587
Fp >230 °F
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka4.54±0.70(Predicted)
optical activity[α]20/D ~ 90°, c = 1 in ethanol
BRN 4202633
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Usage And Synthesis
UsesC2 symmetric ligand for enantioselective catalysis. Easily forms bidentate coordination complexes due to the strong affinity of the oxazoline nitrogen for various metals.
(S,S)-2,2'-METHYLENEBIS(4-PHENYL-2-OXAZOLINE) Preparation Products And Raw materials
Raw materialsDIETHYL MALONIMIDATE DIHYDROCHLORIDE-->L-Phenylglycine-->(S)-(+)-2-Phenylglycinol-->Diethyl malonate

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