| MERCURY(II) TRIFLUOROMETHANESULFONATE Basic information |
| Product Name: | MERCURY(II) TRIFLUOROMETHANESULFONATE |
| Synonyms: | MERCURY(II) TRIFLUOROMETHANESULFONATE (MERCURY TRIFLATE);Mercury(Ⅱ) trifluoroMethanesulfonate;Hg(OTf)2;Methanesulfonic acid,1,1,1-trifluoro-, mercury(2+) salt (2:1);Mercury trifluoromethanesulfonate;MERCURY(II) TRIFLUOROMETHANESULFONATE;MERCURY(II) TRIFLUOROMETHANESULPHONATE;MERCURY TRIFLATE |
| CAS: | 49540-00-3 |
| MF: | C2F6HgO6S2 |
| MW: | 498.73 |
| EINECS: | |
| Product Categories: | metal triflate compounds;triflate;Catalysis and Inorganic Chemistry;Chemical Synthesis;Mercury |
| Mol File: | 49540-00-3.mol |
| MERCURY(II) TRIFLUOROMETHANESULFONATE Chemical Properties |
| Melting point | >350 °C (lit.) |
| solubility | It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene. |
| form | Powder |
| color | White |
| Sensitive | Moisture Sensitive |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3 |
| Stability: | hygroscopic |
| Safety Information |
| Hazard Codes | T+,N,T,C |
| Risk Statements | 26/27/28-33-50/53 |
| Safety Statements | 13-28-36-45-60-61 |
| RIDADR | UN 2025 6.1/PG 2 |
| WGK Germany | 3 |
| Hazard Note | Corrosive/Toxic |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 28521000 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| MERCURY(II) TRIFLUOROMETHANESULFONATE Usage And Synthesis |
| Uses | Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions. |
| MERCURY(II) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials |
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