METHYL 10-UNDECENOATE

CAS No.：111-81-9

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METHYL 10-UNDECENOATE Basic information

Product Name:	METHYL 10-UNDECENOATE
Synonyms:	METHYL UNDECENOATE;METHYL UNDECYLENATE;METHYL 10C-UNDECENOATE;METHYL 10-UNDECENATE;METHYL 10-UNDECENOATE;UNDECYLENIC ACID METHYL ESTER;10-UNDECANOIC ACID METHYL ESTER;10-UNDECENOIC ACID METHYL ESTER
CAS:	111-81-9
MF:	C12H22O2
MW:	198.3
EINECS:	203-910-8
Product Categories:	Biochemicals and Reagents;Building Blocks;C12 to C63;Carbonyl Compounds;Chemical Synthesis;Esters;Aromatic Esters;Fatty Acids and conjugates;Fatty Acyls;Lipids;Methyl Esters;Organic Building Blocks;Unsaturated Fatty Acids and Derivatives
Mol File:	111-81-9.mol

METHYL 10-UNDECENOATE Chemical Properties

Melting point	26-27℃
Boiling point	245 °C (lit.)
density	0.882 g/mL at 25 °C (lit.)
vapor pressure	2.1hPa at 25℃
FEMA	4253 \| METHYL 10-UNDECENOATE
refractive index	n20/D 1.437(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
solubility	H2O: insoluble
form	clear liquid
color	Colorless to Light yellow
Specific Gravity	0.882
Water Solubility	794μg/L at 20℃
JECFA Number	1639
LogP	5.3 at 20℃
CAS DataBase Reference	111-81-9(CAS DataBase Reference)
EPA Substance Registry System	10-Undecenoic acid, methyl ester (111-81-9)

Safety Information

Hazard Codes	Xn,N
Risk Statements	36/37/38-20/22
Safety Statements	26-36/37/39-61-60-24/25
RIDADR	UN 3082 9 / PGIII
WGK Germany	3
HS Code	29161900

MSDS Information

Provider	Language
SigmaAldrich	English

METHYL 10-UNDECENOATE Usage And Synthesis

Chemical Properties	Colorless liquid; oily aroma.
Uses	Methyl 10-undecenoate, unsaturated fatty acid ester, is used to modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane for the preparation of silicone hollow nano/microstructures in water.
Uses	Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate: To prepare bifunctional polymer precursors via hydroformylation reaction. To synthesize α,ω-ester amides via aminocarbonylation in the presence of palladium catalyst. To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.
Definition	ChEBI: A fatty acid methyl ester of 10-undecenoic acid.
Aroma threshold values	Medium strength odor, fatty type
Synthesis Reference(s)	The Journal of Organic Chemistry, 54, p. 3015, 1989 DOI: 10.1021/jo00274a010Tetrahedron, 52, p. 915, 1996 DOI: 10.1016/0040-4020(95)00950-7Synthetic Communications, 3, p. 281, 1973 DOI: 10.1080/00397917308065917
General Description	Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.
Flammability and Explosibility	Nonflammable

METHYL 10-UNDECENOATE Preparation Products And Raw materials

Raw materials	Undecenoic acid-->Ricinoleic acid-->BRN 1762603-->METHYL UNDECYLENATE-->METHYL 10-UNDECYNOATE-->10-Undecenal-->10-UNDECENOYL CHLORIDE
Preparation Products	Undecenoic acid-->Heptaldehyde-->UNDECANAL-->CIS-10-PENTADECENOIC ACID METHYL ESTER (C15:1)-->10-UNDECEN-1-OL-->METHYL 10-HYDROXYDECANOATE-->DIMETHYL OCTADECANEDIOATE-->METHYL 10-METHYLUNDECANOATE-->11-methyldodecanol-->METHYL NONANOATE-->Z-9-TETRADECENAL-->Dimethyl sebacate

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