Other grades of this product :
| 1-METHYL-1-CYCLOHEXENE Basic information |
| 1-METHYL-1-CYCLOHEXENE Chemical Properties |
| Melting point | -119.4°C | | Boiling point | 110-111 °C (lit.) | | density | 0.811 g/mL at 20 °C (lit.) | | vapor pressure | 27.4 at 20.2 °C, 36.4 at 25.0 °C (transpiration method, Verevkin et al., 2000) | | refractive index | n20/D 1.45(lit.) | | Fp | 25 °F | | storage temp. | Sealed in dry,Room Temperature | | solubility | Soluble in benzene and ether (Weast, 1986) and miscible with many hydrocarbons similar in
chemical structure, e.g., cyclohexane, cyclohexene, etc. | | form | Liquid | | color | Clear colorless | | Water Solubility | 52 mg/kg at 25 °C (shake flask-GC, McAuliffe, 1966) | | BRN | 1304483 | | Henry's Law Constant | 8.86 x 10-2 atm?m3/mol at 25 °C (approximate - calculated from water solubility and vapor pressure) | | Stability: | Stable, but may be prone to polymerization. May be stabilized by the addition of around 10 ppm hydroquinone. Highly flammable. Incompatible with strong oxidizing agents. | | InChIKey | CTMHWPIWNRWQEG-UHFFFAOYSA-N | | CAS DataBase Reference | 591-49-1(CAS DataBase Reference) | | EPA Substance Registry System | Cyclohexene, 1-methyl- (591-49-1) |
| Hazard Codes | F,Xn,Xi | | Risk Statements | 11-36/37/38-65 | | Safety Statements | 16-26-36-62 | | RIDADR | UN 3295 3/PG 2 | | WGK Germany | 2 | | Hazard Note | Irritant | | TSCA | Yes | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29021900 |
| 1-METHYL-1-CYCLOHEXENE Usage And Synthesis |
| Chemical Properties | colourless liquid | | Physical properties | Clear, colorless, very flammable, watery liquid with a characteristically unpleasant, aromatic
hydrocarbon-type odor. | | Uses | 1-Methyl-1-cyclohexene (2,3,4,5-Tetrahydrotoluene) was used to study the secondary organic aerosol (SOA) yields from the ozonolysis of cycloalkenes. | | Synthesis Reference(s) | The Journal of Organic Chemistry, 45, p. 917, 1980 DOI: 10.1021/jo01293a030 | | General Description | 1-Methyl-1-cyclohexene (2,3,4,5-Tetrahydrotoluene) is a sterically hindered, unactivated alkene. | | Environmental fate | Photolytic. Atkinson (1985) reported a rate constant of 9.45 x 10-11 cm3/molecule?sec for the
reaction of 1-methylcyclohexene with OH radicals in the atmosphere. | | Purification Methods | Free it from hydroperoxides by passing through a column containing basic alumina or refluxing with cupric stearate, filter and fractionally distil it from sodium. [Vogel J Chem Soc 1332 1938, Cope et al. J Am Chem Soc 79 4729 1957, Beilstein 5 III 197, 5 VI 245.] |
| 1-METHYL-1-CYCLOHEXENE Preparation Products And Raw materials |
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