Menthyl acetate

Menthyl acetate
  • CAS No.:89-48-5
Other grades of this product :
Menthyl acetate Basic information
Product Name:Menthyl acetate
Synonyms:Menthyl acetate;5-methyl-2-(1-methylethyl)-,acetate,(1.alpha.,2.beta.,5.alpha.)-Cyclohexanol;5-methyl-2-(1-methylethyl)-,acetate,(1alpha,2beta,5alpha)-cyclohexano;Cyclohexanol, 5-methyl-2-(1-methylethyl)-, acetate, (1alpha,2beta,5alpha)-;Menthol, acetate, cis-1,3,trans-1,4-;MENTHYL ACETATE 97;MENTHYL ACETATE 97%;Cyclohexanol, 5-methyl-2-(1-methylethyl)-, acetate, (1R,2S,5R)-rel-
CAS:89-48-5
MF:C12H22O2
MW:198.3
EINECS:201-911-8
Product Categories:C12 to C63;Carbonyl Compounds;Esters
Mol File:89-48-5.mol
Menthyl acetate Chemical Properties
Melting point 25°C
alpha D20 -79.42°
Boiling point 228-229 °C (lit.)
density 0.922 g/mL at 25 °C (lit.)
vapor pressure 26Pa at 25℃
FEMA 2668 | MENTHYL ACETATE (ISOMER UNSPECIFIED)
refractive index n20/D 1.447(lit.)
Fp 198 °F
storage temp. -20°C
Water Solubility 17mg/L at 25℃
JECFA Number431
Merck 13,5863
LogP4 at 20℃
CAS DataBase Reference89-48-5(CAS DataBase Reference)
NIST Chemistry ReferenceMenthyl acetate(89-48-5)
EPA Substance Registry System(+/-)-Menthyl acetate (89-48-5)
Safety Information
Hazard Codes N
Risk Statements 51/53
Safety Statements 61
RIDADR UN3082 - class 9 - PG 3 - DOT NA1993 - Environmentally hazardous substances, liquid, n.o.s. HI: all (not BR)
WGK Germany 3
MSDS Information
Menthyl acetate Usage And Synthesis
DescriptionMenthyl acetate has a fresh odor similar to mint and rose (on dilution). It has a characteristic, fresh, pungent flavor, different from menthol (being much milder). It has a cool mouthfeel with only a trace of mint flavor. May be prepared by reacting acetic anhydride with menthol in the presence of anhydrous sodium acetate.
UsesMenthyl acetate may be used in the preparation of 3-amino-2-hydroxyalkanoates via lithium amide-supported Mannich-type reaction of its lithium enolate with PMP-arylaldimines (PMP=p-methoxyphenyl) followed by in situ oxidation with oxaziridine.
UsesMenthyl acetate is in perfumery; emphasizes floral notes, especially that of rose, used in toilet waters having a lavender odor. Has been suggested for flavoring extracts having caraway or mint flavors.
General DescriptionMenthyl acetate (MA), a monoterpene is one of the main constituent of the peppermint essential oil obtained from the leaves of Mentha piperita. It has been reported to show ambulation-promoting effect in mice. Its fumigant and repellent activity has been evaluated on first-instar nymphs of the bloodsucking bug Rhodnius prolixus. The decomposition of MA in an atmospheric flow reactor and a low-pressure flat flame has been investigated by molecular-beam mass spectrometry (MBMS).
Menthyl acetate Preparation Products And Raw materials
Raw materialsSodium acetate-->Peppermint oil

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