| Ethyl glyoxalate Basic information |
| Product Name: | Ethyl glyoxalate |
| Synonyms: | Ethyl glyoxalate 100 liq;Ethyl glyoxylate, 50% solution in toluene;Ethyl oxoacetate Ethyl Glyoxylate Polymer form Ethyl Oxoacetate Polymer form Glyoxalic Acid Ethyl Ester Polymer form;GLYOXYLIC ACID ETHYL ESTER POLYMER FORM;GLYOXYLIC ACID ETHYL ESTER;GLYOXALIC ACID ETHYL ESTER POLYMER FORM;ETHYL OXOACETATE;ETHYL OXOACETATE POLYMER FORM |
| CAS: | 924-44-7 |
| MF: | C4H6O3 |
| MW: | 102.09 |
| EINECS: | 213-105-3 |
| Product Categories: | Aldehydes;Building Blocks;C1 to C6;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Esters;Organic Building Blocks;bc0001 |
| Mol File: | 924-44-7.mol |
| Ethyl glyoxalate Chemical Properties |
| Boiling point | 110°C |
| density | 1.03 g/mL at 20 °C |
| refractive index | 1.4750 |
| Fp | 7°C |
| storage temp. | Refrigerator |
| solubility | Chloroform, Ethyl Acetate |
| form | Oil |
| color | Clear Colorless |
| Water Solubility | Immiscible with water. |
| Sensitive | Air Sensitive |
| BRN | 1209486 |
| CAS DataBase Reference | 924-44-7(CAS DataBase Reference) |
| EPA Substance Registry System | Acetic acid, oxo-, ethyl ester (924-44-7) |
| Safety Information |
| Hazard Codes | F,Xn |
| Risk Statements | 11-38-43-48/20-63-65-67 |
| Safety Statements | 36/37-62-16 |
| RIDADR | UN 1294 3/PG 2 |
| WGK Germany | 3 |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 29183000 |
| MSDS Information |
| Provider | Language |
|---|---|
| Ethyl oxoacetate | English |
| SigmaAldrich | English |
| ALFA | English |
| Ethyl glyoxalate Usage And Synthesis |
| Chemical Properties | Clear colorless to slightly yellow solution |
| Uses | Ethyl glyoxylate is widely used as an intermediate in the synthesis of pharmaceuticals (high reactivity of aldehyde function). It is used in the synthesis of a biodegradable polymer, poly(ethyl glyoxylate). It is actively involved in the Friedel-Crafts alkylation reactions with thiophenes to give the corresponding secondary alcohols. |
| Definition | ChEBI: The ethyl ester of glyoxylic acid. |
| Synthesis Reference(s) | Tetrahedron Letters, 24, p. 2223, 1983 DOI: 10.1016/S0040-4039(00)81889-4 |
| Ethyl glyoxalate Preparation Products And Raw materials |
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