| 2'-Methoxyacetophenone Basic information |
| Product Name: | 2'-Methoxyacetophenone |
| Synonyms: | AKOS BBS-00003280;2-ACETYLANISOLE;2-ACETOANISOLE;2-ACETANISOLE;2'-METHOXYACETOPHENONE;JR-8523, 1-(2-Methoxyphenyl)ethanone, 97%;-Chloro-biphenyl-4-yl)-2-oxo-ethyl]acrylic acid;2-METHOXYACETOPHENONE |
| CAS: | 579-74-8 |
| MF: | C9H10O2 |
| MW: | 150.17 |
| EINECS: | 209-446-2 |
| Product Categories: | Building Blocks;C9;Carbonyl Compounds;Chemical Synthesis;Ketones;Organic Building Blocks;Aromatic Acetophenones & Derivatives (substituted) |
| Mol File: | 579-74-8.mol |
| 2'-Methoxyacetophenone Chemical Properties |
| Melting point | 117–119°C |
| Boiling point | 131 °C18 mm Hg(lit.) |
| density | 1.09 g/mL at 25 °C(lit.) |
| refractive index | n |
| FEMA | 4163 | 2-METHOXYACETOPHENONE |
| Fp | 228 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Chloroform (Sparingly), Methanol (Sparingly) |
| form | Liquid |
| color | Clear slightly yellow to orange or slightly brown |
| Water Solubility | immiscible |
| Sensitive | Light Sensitive |
| JECFA Number | 2042 |
| BRN | 1100602 |
| CAS DataBase Reference | 579-74-8(CAS DataBase Reference) |
| NIST Chemistry Reference | Ortho-methoxyacetophenone(579-74-8) |
| EPA Substance Registry System | Ethanone, 1-(2-methoxyphenyl)- (579-74-8) |
| Safety Information |
| Hazard Codes | Xn,Xi |
| Risk Statements | 22-36/38-36/37/38 |
| Safety Statements | 37/39-26-36 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 29145000 |
| MSDS Information |
| Provider | Language |
|---|---|
| 2-Acetanisole | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 2'-Methoxyacetophenone Usage And Synthesis |
| Chemical Properties | clear slightly yellow to orange or slightly |
| Chemical Properties | Colorless to pale yellow clear liquid; powdery anisic almond phenolic aroma. |
| Uses | 2''-Methoxyacetophenone is a useful building block, often used in the preparation of chalcones, such as the chalcones of 3-benzylidene-2-chlorocyclohex-1-enecarbaldehyde for use as potential anti-proliferative agents. |
| Preparation | Preparation by reaction of dimethyl sulfate with o-hydroxyacetophenone in the presence of sodium hydroxide. |
| Aroma threshold values | Anisic-type, medium strength odor; recommend smelling in a 1.00% solution or less. |
| Taste threshold values | Powdery musty anisic almond taste at 30 ppm in water. |
| Synthesis Reference(s) | Tetrahedron Letters, 22, p. 2605, 1981 DOI: 10.1016/S0040-4039(01)90532-5Journal of the American Chemical Society, 72, p. 5161, 1950 DOI: 10.1021/ja01167a100The Journal of Organic Chemistry, 52, p. 150, 1987 DOI: 10.1021/jo00377a027 |
| 2'-Methoxyacetophenone Preparation Products And Raw materials |
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