Manganese carbonate

Manganese carbonate
  • CAS No.:598-62-9
Other grades of this product :
Manganese carbonate Basic information
Description References
Product Name:Manganese carbonate
Synonyms:RHODOCHROSITE;MANGANESE(+2)CARBONATE;MANGANESE CARBONATE, FOR ANALYTICAL PURPOSE;ManganeseCarbonateAr;Manganese(II) carbonate, tech.;Manganese(Ⅱ)carbonate;Manganese(II)carbonate,Mn44%min;manganese(2+)carbonate(1:1)
CAS:598-62-9
MF:CMnO3
MW:114.95
EINECS:209-942-9
Product Categories:metal carbonate;Inorganics;Inorganic Chemicals;Manganese Salts;Metal and Ceramic Science;Salts
Mol File:598-62-9.mol
Manganese carbonate Chemical Properties
Melting point 350°C (dec.)
density 3.12 g/mL at 25 °C(lit.)
solubility dilute aqueous acid: slightly soluble(lit.)
form Powder
Specific Gravity3.125
color Light brown to violet
Water Solubility Soluble in water(0.065g/L), dilute inorganic acids. Insoluble alcohol.
Merck 14,5726
Solubility Product Constant (Ksp)pKsp: 10.63
Exposure limitsACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3OSHA: Ceiling 5 mg/m3NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability:Stable. Incompatible with strong acids, strong oxidizing agents. May be moisture senstive.
CAS DataBase Reference598-62-9(CAS DataBase Reference)
EPA Substance Registry SystemManganese carbonate (1:1) (598-62-9)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
RTECS OM2470000
TSCA Yes
HS Code 2836991780
Hazardous Substances Data598-62-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Manganese carbonate English
SigmaAldrich English
ALFA English
Manganese carbonate Usage And Synthesis
DescriptionManganese Carbonate is a water-insoluble manganese source which occurs naturally in the form of mineral rhodochrosite. It can easily be converted to other manganese compounds, such as the oxide by heating. Manganese carbonate can be widely applied in various fields. In the field of agriculture, it is commonly used as an additive to plant fertilizers, which is effective to cure the crops with manganese deficiency. It can also be applied in ceramics as a porcelain glaze, glaze colorant and flux and it serves as a catalyst in viscose process. Besides, it has been proved to be used as a hematinic in the field of medicine. Other applications of manganese carbonate involve in health foods, chemical industry and etc.
Referenceshttps://en.wikipedia.org/wiki/Manganese(II)_carbonate https://pubchem.ncbi.nlm.nih.gov/compound/11726#section=Use-and-Manufacturing http://www.chemicalland21.com/industrialchem/inorganic/MANGANESE%20CARBONATE.htm
Chemical PropertiesBrown powder
UsesManganese(II) carbonate occurs in nature as the mineral rhodochrosite [14476-12-1] (manganese spar). This ore also is used to produce manganese dioxide (by electrolytic process). The pure compound is used as gemstones; and as a pigment (manganese white).
UsesAs pigment"manganese white"; drier for varnishes; in feeds.
UsesManganese carbonate (MnCO3) is used in the production of iron ore and as a chemical reagent.
PreparationManganese(II) carbonate is mined from its naturally occurring mineral rhodochrosite. The compound may be prepared in the laboratory as a palepink precipitate by adding sodium bicarbonate to a solution of manganese(II) salt saturated with carbon dioxide. The product obtained is monohydrate, MnCO3•H2O. However, if the carbon dioxide-saturated solution, together with the above monohydrate precipitate, is heated in the absence of atmosphere oxygen, the monohydrate MnCO3•H2O is converted into the anhydrous MnCO3.
General DescriptionManganese(II) carbonate is a chemical compound that has a structure similar to calcite, with octahedral co-ordination symmetry. It is a carbonate that is insoluble in water and on treatment with acid it gives water soluble salts. It is a widely used material in plant fertilization as an additive that cures the magnesium deficiency in crops.
Flammability and ExplosibilityNonflammable

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