Other grades of this product :
| 1-Hexyne Basic information |
| 1-Hexyne Chemical Properties |
| Melting point | -132 °C | | Boiling point | 71-72 °C(lit.) | | density | 0.715 g/mL at 25 °C(lit.) | | vapor pressure | 253 mm Hg ( 37.7 °C) | | refractive index | n20/D 1.399(lit.) | | Fp | −6 °F | | storage temp. | Store at +2°C to +8°C. | | solubility | 0.36g/l (experimental) | | form | Liquid | | Specific Gravity | 0.715 | | color | Clear colorless | | Water Solubility | Miscible with organic solvents. Immiscible with water. | | BRN | 635687 | | Stability: | Stable. Incompatible with strong oxidizing agents. Highly flammable - readily forms explosive mixtures with air. | | CAS DataBase Reference | 693-02-7(CAS DataBase Reference) | | NIST Chemistry Reference | 1-Hexyne(693-02-7) | | EPA Substance Registry System | 1-Hexyne (693-02-7) |
| Hazard Codes | F,Xn,Xi | | Risk Statements | 11-36/37/38-65 | | Safety Statements | 16-26-36-62-9-33-7/9 | | RIDADR | UN 3295 3/PG 2 | | WGK Germany | 3 | | RTECS | MQ9691000 | | F | 10-23 | | Autoignition Temperature | 263 °C | | Hazard Note | Irritant | | TSCA | Yes | | HazardClass | 3 | | PackingGroup | II | | HS Code | 29012980 |
| 1-Hexyne Usage And Synthesis |
| Chemical Properties | colourless liquid | | Uses | 1-Hexyne is used in the preparation of tricyclic isoindolinone scaffold by undergoing hydrozirconation and ring-closing metathesis. It is used to prepare trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate by reacting with thianthrene cation radical tetrafluoroborate. | | General Description | 1-Hexyne reacted with thianthrene cation radical tetrafluoroborate to form trans-1,2-bis(5-thianthreniumyl)alkene tetrafluoroborate. | | Hazard | Probably flammable. | | Purification Methods | Distil it from NaBH4 to remove peroxides. Stand over sodium for 24hours, then fractionally distil it under reduced pressure. Also dry it by repeated vacuum transfer into freshly activated 4A molecular sieves, followed by vacuum transfer onto Na/K alloy and stirring for 1hour before fractionally distilling. [Beilstein 1 IV 1006.] |
| 1-Hexyne Preparation Products And Raw materials |
|
日本语
한국어
Français
Deutsch
España
Türkiye