Sodium trifluoromethanesulfonate

CAS No.：2926-30-9

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Sodium trifluoromethanesulfonate Basic information

Product Name:	Sodium trifluoromethanesulfonate
Synonyms:	SODIUM TRIFLATE;SODIUM TRIFLATE TRIFLUOROMETHANESULFONIC ACID, SODIUM SALT;SODIUM TRIFLUOROMETHANESULFONATE;SODIUM TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID SODIUM SALT;SodiuM trifluoroMethanesulfonate, 98% 5GR;Sodium trifluoromethanesulphonate 98%;Sodiumtrifluoromethanesulphonate98%
CAS:	2926-30-9
MF:	CF3NaO3S
MW:	172.06
EINECS:
Product Categories:	triflate
Mol File:	2926-30-9.mol

Sodium trifluoromethanesulfonate Chemical Properties

Melting point	253-255 °C (lit.)
storage temp.	Inert atmosphere,Room Temperature
form	Powder
color	White to off-white
Water Solubility	soluble
Sensitive	Hygroscopic
Hydrolytic Sensitivity	0: forms stable aqueous solutions
BRN	3728797
InChIKey	KKVTYAVXTDIPAP-UHFFFAOYSA-M
CAS DataBase Reference	2926-30-9(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi,C,Xn
Risk Statements	36/37/38-20/21/22
Safety Statements	26-37/39
WGK Germany	3
F	3-10
Hazard Note	Corrosive
TSCA	No
HS Code	29049090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Sodium trifluoromethanesulfonate Usage And Synthesis

Chemical Properties	White to off-white powder
Uses	Sodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).
Uses	Sodium trifluoromethanesulfonate can be employed as a reagent for the preparation of: Aryl fluorides via silver-catalyzed fluorination of arylstannanes. Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate. It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides.
General Description	Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.

Sodium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials	Hydrogen fluoride-->Methanesulfonic acid
Preparation Products	1-FLUORO-4-(TRIFLUOROMETHYLTHIO)BENZENE-->Ethyl trifluoromethanesulfonate-->4-BROMOPHENYL TRIFLUOROMETHANESULFONATE-->Trifluoromethane-->1-FLUOROPYRIDINIUM TRIFLATE

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