Sodium trifluoromethanesulfonate

Sodium trifluoromethanesulfonate
  • CAS No.:2926-30-9
Other grades of this product :
Sodium trifluoromethanesulfonate Basic information
Product Name:Sodium trifluoromethanesulfonate
Synonyms:SODIUM TRIFLATE;SODIUM TRIFLATE TRIFLUOROMETHANESULFONIC ACID, SODIUM SALT;SODIUM TRIFLUOROMETHANESULFONATE;SODIUM TRIFLUOROMETHANESULPHONATE;TRIFLUOROMETHANESULFONIC ACID SODIUM SALT;SodiuM trifluoroMethanesulfonate, 98% 5GR;Sodium trifluoromethanesulphonate 98%;Sodiumtrifluoromethanesulphonate98%
CAS:2926-30-9
MF:CF3NaO3S
MW:172.06
EINECS:
Product Categories:triflate
Mol File:2926-30-9.mol
Sodium trifluoromethanesulfonate Chemical Properties
Melting point 253-255 °C (lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color White to off-white
Water Solubility soluble
Sensitive Hygroscopic
Hydrolytic Sensitivity0: forms stable aqueous solutions
BRN 3728797
InChIKeyKKVTYAVXTDIPAP-UHFFFAOYSA-M
CAS DataBase Reference2926-30-9(CAS DataBase Reference)
Safety Information
Hazard Codes Xi,C,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-37/39
WGK Germany 3
3-10
Hazard Note Corrosive
TSCA No
HS Code 29049090
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Sodium trifluoromethanesulfonate Usage And Synthesis
Chemical PropertiesWhite to off-white powder
UsesSodium trifluoromethanesulfonate is used in the preparation of N-fluoro-2-methylpyridinium triflate by reaction with dinitrogen difluoride as a reagent. It is also used as a chaotropic mobile phase additive in reversed-phase liquid chromatography (RP-LC).
UsesSodium trifluoromethanesulfonate can be employed as a reagent for the preparation of:
  • Aryl fluorides via silver-catalyzed fluorination of arylstannanes.
  • Ionic liquids such as N, N -dialkylpyrrolidinium triflate, N,N-dialkylimidazolium triflate, and N-alkylpyridinium triflate.
It can be also used as supporting electrolyte in electrochemical O-glycosylation of primary alcohols with O-protected thioglycosides.
General DescriptionSodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions.

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