Product

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE

CAS No.：88284-48-4

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2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Basic information

Product Name:	2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE
Synonyms:	2-(Trimethylsilyl)phenyl Triflate;Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester;2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE;2-(trimethylsilyl)phenyl trifluoromethane-sulfona;2-(Trimethylsilyl)phenyl Triflate Trifluoromethanesulfonic Acid 2-(Trimethylsilyl)phenyl Ester;(TriMethylsilyl)phenyl Triflate;TriMethylsilyl)phenyl trifluoroMethanesulfona;2-(TriMethylsilyl)phenyl trifluoroMethanesulfonate 97%
CAS:	88284-48-4
MF:	C10H13F3O3SSi
MW:	298.35
EINECS:
Product Categories:	Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Organic Triflates;Organic Building Blocks;Sulfur Compounds
Mol File:	88284-48-4.mol

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Chemical Properties

Boiling point	70 °C/2 mmHg (lit.)
density	1.229 g/mL at 25 °C (lit.)
refractive index	n20/D 1.456(lit.)
Fp	205 °F
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	clear liquid
color	Colorless to Light yellow
Specific Gravity	1.229
Hydrolytic Sensitivity	7: reacts slowly with moisture/water
InChIKey	XBHPFCIWRHJDCP-UHFFFAOYSA-N

Safety Information

Hazard Codes	C
Risk Statements	34
Safety Statements	26-27-36/37/39-45
RIDADR	UN 3265 8/PG 2
WGK Germany	3
HazardClass	8
PackingGroup	Ⅱ
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Usage And Synthesis

Physical properties	bp 70 °C/2 mmHg; d 1.229 g mL?1
Uses	2-(Trimethylsilyl)phenyl Triflate is a useful reagent applied in reactions of Polycyclic Arenes, Heteroatom Arylation,Heteroarenes and Benzannulated Heterocycles, Carbon Arylations, etc.
Uses	2-(Trimethylsilyl)phenyl trifluoromethanesulfonate may be used to generate benzyne under mild conditions of simple fluoride treatment at room temperature.
General Description	2-(Trimethylsilyl)phenyl trifluoromethanesulfonate is an important ortho-benzyne precursor in aryne chemistry.

2-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials	Diethyl ether-->Sodium-->Toluene-->n-Butyllithium-->Chlorotrimethylsilane-->Trifluoromethanesulfonic anhydride-->2-Chlorophenol
Preparation Products	Triphenylene-->Thianaphthene-->2-NITRO-6(5H)-PHENANTHRIDINONE-->3-Chloro-1,2-benzisothiazole-->4-Fluoro-N,N-diphenylbenzenamine-->1,2-Diiodobenzene-->1H-Indazole-3-carboxylic acid, 1-phenyl-, ethyl ester-->PHENYL P-TOLYL SULFONE-->DIETHYL PHENYLPHOSPHONATE

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