| 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Basic information |
| Product Name: | 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE |
| Synonyms: | 1-(Trimethylsilyloxy)-1-phenylethene;1-Phenyl-1-trimethylsiloxyethene;1-Phenylvinyl trimethylsilyl ether;(1-Phenylethenyloxy)trimethylsilane;[(1-Phenylethenyl)oxy]trimethylsilane;à-(trimethylsiloxy)styrene;α-(trimethylsiloxy)styrene;1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 97% |
| CAS: | 13735-81-4 |
| MF: | C11H16OSi |
| MW: | 192.33 |
| EINECS: | 237-308-1 |
| Product Categories: | Building Blocks;Chemical Synthesis;Monoalkoxysilanes;Enol Ethers;Organic Building Blocks;Oxygen Compounds;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Si-O Compounds;Synthetic Organic Chemistry |
| Mol File: | 13735-81-4.mol |
| 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Chemical Properties |
| Melting point | 122-123 °C |
| Boiling point | 88-89 °C/11 mmHg (lit.) |
| density | 0.938 g/mL at 25 °C (lit.) |
| vapor density | >1 (vs air) |
| refractive index | n |
| Fp | 174 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Light orange to Yellow |
| Specific Gravity | 0.938 |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 1306914 |
| CAS DataBase Reference | 13735-81-4(CAS DataBase Reference) |
| EPA Substance Registry System | Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| WGK Germany | 3 |
| F | 10-21 |
| TSCA | No |
| HS Code | 2931900090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Usage And Synthesis |
| Uses | 1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates. |
| Uses | 1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
|
| General Description | 1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants. |
| 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Preparation Products And Raw materials |
| Preparation Products | diethyl 2,3-diisopropylsuccinate-->4-Hydroxy-6-methyl-2-pyrone-->1-PHENYL-1-CYCLOPROPANOL |
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