2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • CAS No.:61676-62-8
Other grades of this product :

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Basic information
Product Name:2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Synonyms:Isopropoxyboronic acid pinacol;Isopropoxyboronic acid picol ester;Isopropoxyboronic a;Isopropoxyboronic aci;2-ISOPROPOXY-4,4,5,5-TETRAMETHYL-1,3,2-DIOABOROLANE;2-Isopropoxyboronic acid, pinacol cyclic ester;sopropoxyboronic acid pinacol ester;Isopropoxyboronic acid pinacol ester    2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS:61676-62-8
MF:C9H19BO3
MW:186.06
EINECS:612-189-2
Product Categories:Boric Acid|      Boric Acid Ester|    Potassium  Trifluoroborate;B (Classes of Boron Compounds);Boric Acid Esters;Boric Acid Triesters;Boronic  Acids  and  Derivatives;Organoborates;Boronic ester;Organoborons;Organometallic  Reagents;Organic boronic acid
Mol File:61676-62-8.mol
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Chemical Properties
Boiling point 73 °C15 mm Hg(lit.)
density 0.912 g/mL at 25 °C(lit.)
refractive index n20/D1.409(lit.)
Fp 109 °F
storage temp. Inert atmosphere,2-8°C
form Liquid
Specific Gravity0.912
color Colorless
Water Solubility Soluble in water.
Sensitive Moisture Sensitive
BRN 1906370
InChIKeyMRWWWZLJWNIEEJ-UHFFFAOYSA-N
CAS DataBase Reference61676-62-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38
Safety Statements 16-26-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
HazardClass 3
PackingGroup III
HS Code 29209090
MSDS Information
ProviderLanguage
Isopropyl pinacolyl borateEnglish
SigmaAldrichEnglish
ALFAEnglish
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Usage And Synthesis
Chemical PropertiesColorless liquid
Uses2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane can be used as a reagent to borylate arenes and to prepare fluorenylborolane.It can also be used in the synthesis of following intermediates for generating conjugated copolymers:
  • 9,9-Dioctyl-2,7-bis(4,4,5,5-tetramethyl1,3,2-dioxaborolane-2-yl)dibenzosilole.

  • 3,9-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-5,11-di(1-decylundecyl)indolo[3,2-b]carbazole.

  • 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene.

  • 2,7-Bis(4′,4′,5′,5′-tetramethyl-1′,3′,2′-dioxaborolan-2′-yl)-N-9′′-heptadecanylcarbazole.

Usessuzuki reaction
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Preparation Products And Raw materials
Preparation Products4'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl-4-carbonitrile-->Benzo[b]thiophene-3-boronic acid pinacol ester, 95%-->3-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)PYRAZOLO[1,5-A]PYRIDINE-->4-Difluoromethoxyphenylboronic acid pinacol ester-->3-Hydroxy-2,3-diMethylbutan-2-yl hydrogen (2,6-diMethylpyridin-3-yl)boronate-->3-CHLOROPHENYLBORONIC ACID, PINACOL ESTER-->1-Ethyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole-->1-(2-Methoxyethyl)-4-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrazole-->2-(1-NAPHTHYLENE)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE-->3-METHYLTHIOPHENE-2-BORONIC ACID PINACOL ESTER-->3-TRIFLUOROMETHYLPHENYLBORONIC ACID, PINACOL ESTER-->2-(Chloromethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane-->(DIMETHYLPHENYLSILYL)BORONIC ACID PINAC&-->9-Octyl-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

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