Product

2-HYDROXYACETOPHENONE

CAS No.：582-24-1

Other grades of this product :

2-HYDROXYACETOPHENONE Basic information

Product Name:	2-HYDROXYACETOPHENONE
Synonyms:	2-hydroxy-1-phenyl-ethanon;2-Hydroxy-1-phenylethanone;2-Hydroxyethylphenyl ketone;Acetophenone, 2-hydroxy-;Acetophenone, alpha-hydroxy-;Ethanone, 2-hydroxy-1-phenyl-;Glycolophenone;Methanol, benzoyl-
CAS:	582-24-1
MF:	C8H8O2
MW:	136.15
EINECS:	209-480-8
Product Categories:	C7 to C8;Carbonyl Compounds;Ketones
Mol File:	582-24-1.mol

2-HYDROXYACETOPHENONE Chemical Properties

Melting point	86-89 °C (lit.)
Boiling point	126 °C / 12mmHg
density	1.0963
refractive index	1.5470 (estimate)
storage temp.	Sealed in dry,Room Temperature
pka	13.09±0.10(Predicted)
form	Powder
color	Slightly yellow to orange
Water Solubility	Soluble in water, ether, ethanol, chloroform.
Sensitive	Air & Moisture Sensitive
CAS DataBase Reference	582-24-1(CAS DataBase Reference)
NIST Chemistry Reference	«alpha»-Hydroxyacetophenone(582-24-1)
EPA Substance Registry System	Ethanone, 2-hydroxy-1-phenyl- (582-24-1)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	3
TSCA	Yes
HS Code	29144000

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

2-HYDROXYACETOPHENONE Usage And Synthesis

Chemical Properties	slightly yellow to orange powder
Uses	2-Hydroxyacetophenone can be used to produce 2-hydroxy-1-phenyl-ethanone-(1)-oxime by heating. It is used as pharmaceutical intermediate.
Uses	2-Hydroxyacetophenone can be used as a starting material for the synthesis of: Enantioselective 1R-phenyl-1,2-ethanediol in the presence of a rhodium(III) catalyst by asymmetric transfer hydrogenation. Copper(II) complexes of 2-hydroxyacetophenone N-substituted thiosemicarbazones. Chromium, molybdenum, and ruthenium complexes of 2-hydroxyacetophenone Schiff bases. 2-Hydroxyacetophenone-aroyl hydrazone derivatives for inhibition of copper corrosion in nitric acid.
Definition	ChEBI: 2-hydroxyacetophenone is a monohydroxyacetophenone that is acetophenone in which one of the methyl hydrogens has been replaced by a hydroxy group. It is a primary alcohol, a primary alpha-hydroxy ketone and a monohydroxyacetophenone.

2-HYDROXYACETOPHENONE Preparation Products And Raw materials

Preparation Products

1,2-Ethanedione, 1-phenyl-2-(1-piperidinyl)- Piperidine, 1-(oxophenylacetyl)- (9CI)-->Ethyl benzoate-->2-Bromo-2′-hydroxyacetophenone-->1-Phenyl-1,2-ethanediol

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