4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one

4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one
  • CAS No.:28664-35-9
Other grades of this product :
4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one Basic information
Product Name:4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one
Synonyms:4,5-dimethyl-3-hydroxy-2,5-dihydrofuran-2-one AKA sugar lactone;CARAMEL FURANONE (3% IN TRIACETIN);3-HYDROXY-4,5-DIMETHYL-2(5H)-FURANONE;4,5-DIMETHYL-3-HYDROXY-2,5-DIHYDROFURAN-2-ONE;4,5-DIMETHYL-3-HYDROXY-2(5H)-FURANONE;FEMA 3634;Fenugreck Lactone;FENUGREEK LACTONE
CAS:28664-35-9
MF:C6H8O3
MW:128.13
EINECS:249-136-4
Product Categories:food additives;food additive
Mol File:28664-35-9.mol
4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one Chemical Properties
Melting point 26-29 °C(lit.)
Boiling point 184 °C(lit.)
density 1.049 g/mL at 25 °C
refractive index n20/D 1.491(lit.)
FEMA 3634 | 4,5-DIMETHYL-3-HYDROXY-2,5-DIHYDROFURAN-2-ONE
Fp >230 °F
storage temp. Sealed in dry,2-8°C
form neat
pka9.28±0.40(Predicted)
JECFA Number243
InChIKeyUNYNVICDCJHOPO-UHFFFAOYSA-N
CAS DataBase Reference28664-35-9(CAS DataBase Reference)
NIST Chemistry Reference2(5H)-furanone, 3-hydroxy-4,5-dimethyl-(28664-35-9)
EPA Substance Registry System2(5H)-Furanone, 3-hydroxy-4,5-dimethyl- (28664-35-9)
Safety Information
Hazard Codes Xn
Risk Statements 20/22
Safety Statements 36
WGK Germany 3
HS Code 29329990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one Usage And Synthesis
Chemical Propertiesclear yellow liquid
Chemical Properties3-Hydroxy-4,5-dimethyl-2(5H)-furanone was found in, for example, fenugreek, coffee, sake, and florsherry. Its aroma characteristic changes from caramel-like at low concentrations to curry-like at high concentrations. A method described for its preparation comprises condensation of ethyl propionate with diethyl oxalate and reaction of the intermediately formed diethyl oxalylpropionate with acetaldehyde. Acidic decarboxylation of the ethyl 4,5-dimethyl-2,3-dioxodihydrofuran-4-carboxylate gives the title compound.
OccurrenceReported found in roasted Virginia tobacco, beef broth, beer, sherry, botryized wine, coffee, tea, fenugreek, sake and rice wine.
Aroma threshold valuesAroma characteristics at 1.0%; sweet, strong brown, cyclotene and maple like, caramel, toffee, maltol-like and burnt, brown sugar fenugreek-like, cooked and syrupy.
Taste threshold valuesTaste characteristics at 5–25 ppm; sweet, caramel, maple, walnut, brown sugar, nutty, cotton candy, fenugreek and celery-like, rum, roasted meaty with a honey nuance
4,5-Dimethyl-3-hydroxy-2,5-dihydrofuran-2-one Preparation Products And Raw materials

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