Product

CIS-1,4-HEXADIENE

CAS No.：7318-67-4

Other grades of this product :

CIS-1,4-HEXADIENE Basic information

Product Name:	CIS-1,4-HEXADIENE
Synonyms:	CIS-1,4-HEXADIENE;(4Z)-1,4-Hexadiene;(z)-1,4-hexadiene;1,4-Hexadiene, (Z)-;Nsc157585;cis-1,4-Hexadiene >=99.0%;(z)-4-hexadiene;(Z)-CH2=CHCH2CH=CHCH3
CAS:	7318-67-4
MF:	C6H10
MW:	82.14
EINECS:	230-783-6
Product Categories:	Acyclic;Alkenes;Organic Building Blocks
Mol File:	7318-67-4.mol

CIS-1,4-HEXADIENE Chemical Properties

Melting point	-94.9°C (estimate)
Boiling point	65-66 °C (lit.)
density	0.707 g/mL at 20 °C (lit.)
refractive index	n20/D 1.415
Fp	-46 °C
BRN	1839519

Safety Information

Hazard Codes	F,Xn
Risk Statements	11-65
Safety Statements	16-62
RIDADR	UN 2458 3/PG 2
WGK Germany	3
RTECS	MM1997000

MSDS Information

Provider	Language
SigmaAldrich	English

CIS-1,4-HEXADIENE Usage And Synthesis

General Description

cis-1,4-Hexadiene can be synthesized from the cobalt-catalyzed reaction between butadiene and ethylene. The reaction of this hydrocarbon with Fe(CO)₅ affords the trans-1,3-hexadiene-iron tricarbonyl complex (I), plus a small amount of the trans,trans-2,4-hexadiene complex(II). Mechanism of the conversion of cis-1,4-hexadiene to trans-2-methyl-1,3-pentadiene, via rearrangement in the presence of a nickel catalyst has been investigated.

CIS-1,4-HEXADIENE Preparation Products And Raw materials

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