3-Bromo-1-benzothiophene

3-Bromo-1-benzothiophene
  • CAS No.:7342-82-7
Other grades of this product :
3-Bromo-1-benzothiophene Basic information
Product Name:3-Bromo-1-benzothiophene
Synonyms:TIMTEC-BB SBB003415;3-BROMOTHIANAPHTHENE;3-BROMOBENZO[B]THIOPHENE;3-BROMOBENZOTHIOPHENE;3-BROMO-1-BENZOTHIOPHENE;BUTTPARK 147\16-62;3-Bromo-1-benzothiophene ,97%;Benzo[b]thiophene, 3-broMo-
CAS:7342-82-7
MF:C8H5BrS
MW:213.09
EINECS:
Product Categories:alkyl bromide;Halides;Thiophenes & Benzothiophenes;Thiophenes & Benzothiophenes
Mol File:7342-82-7.mol
3-Bromo-1-benzothiophene Chemical Properties
Melting point 146-156 °C
Boiling point 269 °C/752.5 mmHg (lit.)
density 1.629 g/mL at 25 °C (lit.)
refractive index n20/D 1.668(lit.)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Sparingly Soluble (0.14 g/L) (25°C).
form clear liquid
color Light yellow to Brown
CAS DataBase Reference7342-82-7(CAS DataBase Reference)
NIST Chemistry ReferenceBenzo[b]thiophene, 3-bromo-,(7342-82-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HazardClass IRRITANT
HS Code 29349990
MSDS Information
ProviderLanguage
SigmaAldrich English
3-Bromo-1-benzothiophene Usage And Synthesis
Chemical PropertiesColorless to yellow to red liquid
UsesAntifungal activity of synthetic di (hetero) arylamines based on the benzo [b] thiophene moiety.
Uses3-Bromothianaphthene may be used in the synthesis of (benzo[b]thiophen-3-yl)trimethylstannane.
General Description3-Bromothianaphthene is a heteroaryl halide. It undergoes Suzuki-Miyaura reaction with phenylboronic acid (PBA) or 3-thienylboronic acid in the presence of a novel heterogeneous Pd catalyst [Pd@PDEB, PDEB=poly(1,3-diethynylbenzene)]. The substitution reaction of 3-bromothianaphthene with piperidine to form 3-piperidinothianaphthene as the major product has been reported.

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