TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE

TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
  • CAS No.:69227-47-0
Other grades of this product :
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Basic information
Product Name:TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
Synonyms:tris(3,5-dimethylphenyl)-phosphin;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE;TRIS(3,5-XYLYL)PHOSPHINE;TRI(3,5-XYLYL)PHOSPHINE;Tris(3,5-dimethylphenyl)phosphine,98%;TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE, 97+%;Tri(3,5-dimethylphenyl)phosphine;Tris(3,5-dimethylphenyl)phosphineTris(3,5-xylyl)phosphine
CAS:69227-47-0
MF:C24H27P
MW:346.44
EINECS:624-162-2
Product Categories:Aryl Phosphine;Achiral Phosphine;Ligand;Catalysis and Inorganic Chemistry;Phosphine Ligands;organophosphorus ligand;Phosphorus Compounds
Mol File:69227-47-0.mol
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Chemical Properties
Melting point 160-165 °C
Boiling point 474.1±45.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form crystal
color white
EPA Substance Registry SystemPhosphine, tris(3,5-dimethylphenyl)- (69227-47-0)
Safety Information
Hazard Codes Xn
Risk Statements 22
Safety Statements 26-36/37/39-22
WGK Germany 3
TSCA Yes
HS Code 29310099
MSDS Information
ProviderLanguage
ACROS English
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
UsesCatalyst for:
  • Cu / diphosphine-catalyzed asymmetric hydrogenation of heteroaromatic ketones and enones
  • Highly selective rhodium-catalyzed hydrogenation reactions
  • Classical versus kinetic resolution in preparation of privileged silicon-stereogenic silanaphthalenes
Used for kinetic resolution of donor-functionalized secondary alcohols via Cu-H-catalyzed stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanesUsed for comparative studies of conformational rigidity of silicon-stereogenic silanes in asymmetric catalysis
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE Preparation Products And Raw materials

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