| 1-Boc-Pyrrolidine Basic information |
| Product Name: | 1-Boc-Pyrrolidine |
| Synonyms: | N-1-BOC-Pyrrolidone;Tert-Butylpyrrolidine-1-Carboxylate;Pixantrone-bis-(2’1-pyrrolidinecarboxylic acid tert-butyl ester;1-Pyrrolidinecarboxylic Acid 1,1-DiMethylethyl Ester;NT 0186;N-tert-Butoxycarbonylpyrrolidine;N-BOC-Tetrahydro pyrrole |
| CAS: | 86953-79-9 |
| MF: | C9H17NO2 |
| MW: | 171.24 |
| EINECS: | 617-940-8 |
| Product Categories: | Pyrrole&Pyrrolidine&Pyrroline |
| Mol File: | 86953-79-9.mol |
| 1-Boc-Pyrrolidine Chemical Properties |
| Boiling point | 80 °C/0.2 mmHg (lit.) |
| density | 0.977 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | 187 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform, Methanol |
| form | Oil |
| pka | -1.28±0.20(Predicted) |
| color | Clear Colorless |
| BRN | 4664750 |
| CAS DataBase Reference | 86953-79-9(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NA 1993 / PGIII |
| WGK Germany | 3 |
| Hazard Note | Irritant |
| HS Code | 29339900 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| 1-Boc-Pyrrolidine Usage And Synthesis |
| Chemical Properties | liquid |
| Uses | 1-Boc-pyrrolidine is a boc-protected cyclic amine used as a building block in the preparation of diastereomers by usually undergoing α'-lithiations and electrophilic substitution reactions. |
| Uses | N-Boc-pyrrolidine may be used in the synthesis of the following:
|
| General Description | N-Boc-pyrrolidine is an N-substituted pyrrolidine. It is reported that the reactivity of N-Boc-pyrrolidine towards C-H insertion reaction is 2000 times more than cyclohexane. It undergoes α-arylation in the presence of a palladium catalyst with high enantioselectivity. |
| 1-Boc-Pyrrolidine Preparation Products And Raw materials |
| Preparation Products | N-BOC PRROLIDIN-2-OL-->2-HYDROXYMETHYL-PYRROLIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER |
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