2-(Bromomethyl)naphthalene

2-(Bromomethyl)naphthalene
  • CAS No.:939-26-4
Other grades of this product :
2-(Bromomethyl)naphthalene Basic information
Product Name:2-(Bromomethyl)naphthalene
Synonyms:2-(BROMOMETHYL)NAPHTHALENE;2-BMN;BROMOMETHYLNAPTHALENE-2;2-Bromomethylnaphthalene98%;2-(Bromomethyl)naphthalene,96%;(2-Naphtylmethyl) bromide;Naphthalene, 2-(bromomethyl)-;2-naphthylmethyl bromide
CAS:939-26-4
MF:C11H9Br
MW:221.09
EINECS:213-359-5
Product Categories:Naphthalene series;Aryl;Naphthalene derivatives;C9 to C12;Halogenated Hydrocarbons
Mol File:939-26-4.mol
2-(Bromomethyl)naphthalene Chemical Properties
Melting point 51-54 °C(lit.)
Boiling point 213 °C100 mm Hg(lit.)
density 1.3971 (rough estimate)
refractive index 1.6411 (estimate)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), Ethyl Acetate (Very Slightly)
form Fine Crystalline Powder
color Slightly yellow to light beige
Water Solubility Soluble in water (reacts), and chloroform.
BRN 636546
CAS DataBase Reference939-26-4(CAS DataBase Reference)
NIST Chemistry ReferenceNaphthalene, 2-(bromomethyl)-(939-26-4)
Safety Information
Hazard Codes C,Xi
Risk Statements 34-43-36/37/38-36
Safety Statements 26-28-36/37/39-45-37-27
RIDADR UN 3261 8/PG 2
WGK Germany 3
10-21
Hazard Note Corrosive/Keep Cold
HazardClass 8
PackingGroup II
HS Code 29033036
MSDS Information
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2-(Bromomethyl)naphthalene Usage And Synthesis
Chemical PropertiesWhite to cream solid
UsesIt is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.
Uses2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).
Purification MethodsDissolve the bromo compound in toluene, wash it with saturated aqueous NaHCO3, dry (Mg SO4), evaporate, fractionally distil the residue and recrystallise the solidified distillate from EtOH. [Chapman & Williams J Chem Soc 5044, 1952, Bergmann & Szmuszkovicz Bull Soc Chim Fr 20 566 1953, Beilstein 5 IV 1698.]

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